- Synthesis of stereospecifically labeled 3,6-dideoxyhexoses.
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Preparations of ascarylose (3,6-dideoxy-L-arabino-hexose), abequose (3,6-dideoxy-D-xylo-hexose), and paratose (3,6-dideoxy-D-ribo-hexose) with stereospecific deuterium labeling at C-3 are discussed. The methods used to synthesize these sugars, such as the
- Russell,Weigel,Han,Liu
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- SYNTHESIS OF STEREOSPECIFICALLY LABELLED CARBOHYDRATES III1,2: PREPARATION OF (3S)- AND (3R)-3-2H1PARATOSE
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Two synthetic pathways producing methyl 3,6-dideoxy-α-D-ribo-hexose (methyl paratose) labeled stereospecifically with deuterium at the 3S (1) and 3R (2) position, respectively, are described.
- Russell, Raymond N.,Liu, Hung-wen
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p. 5729 - 5732
(2007/10/02)
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