A Study of the Photochemically Induced Electron-Transfer Reactions Between Pyridinedicarbonitriles and Primary and Secondary Aliphatic Amines
A study on the photochemically induced electron-transfer from primary and secondary aliphatic amines as donors to pyridinecarbonitriles as the acceptor is reported.A comparison between the substitution positions and the spin density distributions, obtained via teoretical calculations using the 6-31+G basis set, shows some discrepancies, and forms the basis of a hypothesis on the mechanism of the reaction.
Bernardi, Rosanna,Caronna, Tullio,Poggi, Gabriella,Vittimberga, Bruno M.
p. 903 - 908
(2007/10/02)
A Study of the Photochemically Induced Reaction of Pyridine-2,4-dicarbonitrile with Primary and Secondary Amines. A Direct Synthesis of Aminocyanopyridines
A novel synthesis of alkylaminopyridinecarbonitriles by a photoinitiated substitution reaction between pyridine-2,4-dicarbonitrile and certain amines is described.The mechanism is discussed.
Bernardi, Rosanna,Caronna, Tullio,Morrocchi, Sergio,Ursini, Maurizio,Vittimberga, Bruno M.
p. 97 - 100
(2007/10/02)
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