Asymmetric Induction in Nitrone Cycloadditions: A Total Synthesis of Acivicin by Double Asymmetric Induction
A total synthesis of acivicin, (αS,5S)-α-amino-3-chloro-4,5-dihydroisoxazole-5-acetic acid, has been achieved in 39percent overall yield from a derivative of (2S)-vinylglycine.The required diastereomer was obtained in an extremaly efficient manner = 19
Mzengeza, Shadreck,Whitney, Ralph Allen
p. 4074 - 4081
(2007/10/02)
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