- Inorganic/organic small molecular semiconductor self-assembly to functional core-shell nanoarchitectures for ultrasensitive chemiresistors to aniline vapor
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We developed a new method combining the in situ liquid-solid phase reaction and self-assembly in solution to synthesize novel inorganic/organic small molecular semiconductor core-shell nanoparticles of ZnS/PTCDA (ZPNPs). This method is a one-step process which can produce stoichiometric inorganic/organic core-shell nanoparticles and does not introduce any impurity. The film of ZPNPs exhibited an ultrasensitive detection of aniline vapor. The film of ZPNPs can highly selectively distinguish aniline vapor from many volatile organic compounds and water due to the strong synergistic interactions of π-π and hydrogen-bonds between electron donor (aniline) and acceptor (PTCDA) molecules, in which the detection limit was lowered to 100 ppb at room temperature. This journal is the Partner Organisations 2014.
- Wang, Ke,Yang, Hui,Qian, Xuemin,Xue, Zheng,Li, Yongjun,Liu, Huibiao,Li, Yuliang
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- A 3, 9 - perylene dicarboxylic acid preparation method
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The invention discloses a 3, 9 - perylene dicarboxylic acid of preparation method, specific step is ice-acetic acid in a solvent, in the dihydro e is obtained under the action of the sodium dichromate of 1, 8 - naphthalenedicarboxylic anhydride; 1, 8 - naphthalenedicarboxylic anhydride in saturated ammonia under the action of the acylation to obtain the 1, 8 - naphthalene asia amide; 1, 8 - naphthalene asia amide in potassium hydroxide and anhydrous sodium acetate manufacturing of the alkaline environment in the alkaline environment in C - C under high-temperature conditions obtained by coupling the 3, 4, 9, 10 - perylenetetracarboxylic acid diimide; 3, 4, 9, 10 - perylenetetracarboxylic acid diimide in under the action of the strong acid is converted into the 3, 4, 9, 10 - [...]; 3, 4, 9, 10 - [...] in microwave reactor in alkaline hydrolysis by the decarboxylation of 3, 9 - perylene dicarboxylic acid. The invention synthetic process more economic, environmental protection, high-efficient and simple.
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- Preparation method and application of novel perylene acid medicinal molecule with antineoplastic activity
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The invention discloses a preparation method and application of a novel perylene acid medicinal molecule with antineoplastic activity, and belongs to the technical field of pharmaceutical synthesis. The novel perylene acid medicinal molecule with antineoplastic activity is characterized by having the structural formula as shown in the description. The invention also provides a preparation method of the novel perylene medicinal molecule with the antineoplastic activity. The prepared perylene medicinal molecule has higher inhibiting activity for human cervical carcinoma Hela cells, human breastcancer MDA-MB-231 cells and human liver cancer HepG2 cells, and has the potential of becoming an antineoplastic medicament.
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- Preparation method and application of novel perylene drug molecule with biological activity
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The invention discloses a preparation method and application of a novel perylene drug molecule with the biological activity, and belongs to the technical field of medicine synthesis. According to thekey points of the technical scheme of the preparation method and application of the novel perylene drug molecule, the structural formula of the perylene drug molecule with the biological activity is as shown in the specification, wherein R is O or S. The invention further relates to the preparation method for the novel perylene drug molecule with the biological activity. The perylene drug moleculeprepared through the preparation method has good inhibitory activity on human cervical cancer hHela cells, human breast cancer MDA-MB-231 cells and human liver cancer HepG2 cells, is relatively low in toxicity on human normal cells and has the potential of becoming an anti-tumor drug.
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- Preparation method of Lumogen Red F300
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The invention relates to Lumogen Red F300, in particular to a preparation method of the Lumogen Red F300. The preparation method comprises the following steps that 1,6,7,12-tetrabromo-3,4,9,10-perylenetetracarboxylic dianhydride is prepared; a 1,6,7,12-tetraphenoxy-3,4,9,10-perylenetetracarboxylic potassium aqueous solution is prepared; and an amination reaction is performed. The preparation method is more scientific and reasonable; and the color fastness is relatively higher, so that the Lumogen Red F300 is close to functional dye.
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Paragraph 0026; 0034; 0035; 0036; 0042; 0046
(2017/07/20)
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- Method for preparing perylene-3,4,9,10-tetracarboxylic dianhydride through superacid catalytic hydrolysis
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The invention relates to preparation of perylene-3,4,9,10-tetracarboxylic dianhydride, in particular to a method for preparing perylene-3,4,9,10-tetracarboxylic dianhydride through superacid catalytic hydrolysis. According to the method, 300 parts of perylene-3,4,9,10-tetracarboxylic dianhydride are added into 2000 parts of 90 percent-100 percent concentrated sulfuric acid; temperature rise is performed to 60 to 120 DEG C; heat insulation is performed until the materials are totally dissolved; then, the temperature is lowered to 80 DEG C; 4.5 parts of superacid catalysts are slowly added; the temperature is raised to 125 DEG C; heat insulation is performed for 8h; the temperature is lowered to 60 DEG C; filtering is performed; 1500 parts of 85-percent concentrated sulfuric acid are used for washing filter cake; then, the filter cake is transferred into 3000 parts of water; after uniform stirring, filtering is performed; water is used for washing into a neutral state; the perylene-3,4,9,10-tetracarboxylic dianhydride is obtained. The consumption of sulfuric acid can be reduced; the quantity of sulfur dioxide generated and discharged in the hydrolysis reaction process is reduced.
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Paragraph 0015-0032
(2017/07/21)
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- Self-assembly of semifluorinated minidendrons attached to electron-acceptor groups into pyramidal columns
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The synthesis and self-assembly of twelve semifluorinated first-generation dendrons or minidendrons attached to electron-acceptor (n-type) groups generated from various combinations of eight acceptors and three dendrons arc reported. Dendrons attached to small electron-acceptor molecules mediate their self-assembly into π-stacks located in the center of a supramolecular helical pyramidal column with the long axis of the acceptor perpendicular to the long axis of the column. Dendrons attached to large electron-acceptor molecules, such as perylene bisimide, mediate the assembly of their acceptors in an unprecedented arrangement of π-stacks that have the long axis of the acceptors parallel to the long axis of the supramolecular pyramidal column. All supra_molecular columns self-organize into various periodic columnar arrays that exhibit liquid-crystalline phases, crystalline phases, or a liquid-crystalline phase with enhanced intracolumnar order. The present study demonstrates the simplicity and the versatility of the concept of assembly of π-type electroactive groups mediated by semifluorinated dendrons and assesses the scope and limitations of this supramolecular strategy.
- Percec, Virgil,Aqad, Emad,Peterca, Mihai,Imam, Mohammad R.,Glodde, Martin,Bera, Tusha K.,Miura, Yoshiko,Balagurusamy, Venkatachalapathy S. K.,Ewbank, Paul C.,Wuerthner, Frank,Heiney, Paul A.
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p. 3330 - 3345
(2008/02/07)
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- Single-molecule spectroscopy of interfacial electron transfer
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It is widely appreciated that single-molecule spectroscopy (SMS) can be used to measure properties of individual molecules which would normally be obscured in an ensemble-averaged measurement. In this report we show how SMS can be used to measure photoinduced interfacial electron transfer (IET) and back electron transfer rates in a prototypical chromophore-bridge-electrode nonadiabatic electron transfer system. N-(1-hexylheptyl)-N′ -(12-carboxylicdodecyl)perylene-3,4,9,10-tetracarboxylbisimide was synthesized and incorporated into mixed self-assembled monolayers (SAMs) on an ITO (tin-doped indium oxide, a p-type semiconductor) electrode. Single-molecule fluorescence time trajectories from this system reveals "blinks", momentary losses in fluorescence (>20 ms to seconds in duration), which are attributed to discrete electron transfer events: electron injection from the perylene chromophore into the conduction band of the ITO leads to the loss of fluorescence, and charge recombination (back electron transfer) leads to the return of fluorescence. Such blinks are not observed when an electrode is not present. The fluorescence trajectories were analyzed to obtain the forward and back electron rates; the measured rates are found to lie in the millisecond to second regime. Different rates are observed for different molecules, but the lifetime distributions for the forward or back electron transfer for any given molecule are well fit by single exponential kinetics. The methodology used is applicable to a wide variety of systems and can be used to study the effects of distance, orientation, linker, environment, etc. on electron transfer rates. The results and methodology have implications for molecular electronics, where understanding and controlling the range of possible behaviors inherent to molecular systems will likely be as important as understanding the individual behavior of any given molecule.
- Holman, Michael W.,Liu, Ruchuan,Adams, David M.
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p. 12649 - 12654
(2007/10/03)
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- Perylenamidine-imide Dyes
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Perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride-9,10-imides are condensed with primary diamines to a number of new basic chromophores with amidine-imide structures.Lightfast dyes are obtained which exhibit a strong fluorescence in solution.The absorption and fluorescence spectra of the title compounds are bathochromically shifted compared to those of the perylene dyes. - Key Words: Dyes, fluorescent / Perylene derivatives / Heterocyclic rings
- Langhals, Heinz,Sprenger, Sylvia,Brandherm, Marie-Theres
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p. 481 - 486
(2007/10/02)
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- N-cyanoimides
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Polyfunctional N-cyanoimides and their precursors and derivatives are disclosed along with methods for their preparation and interconversion. Also disclosed are curable compositions comprising the N-cyanoimides or poly(amide-cyanoamides) and reactive diluents as well as novel dianhydrides, polyimides, and poly(amide-cyanoamides) and methods for making them.
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- Diamines and photosensitive polyimides made therefrom
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Disclosed is an aromatic diamine having the general formula where A is a group containing at least one aromatic ring, each Y is independently selected from or -OR, R is a group containing at least one olefinically unsaturated group, R' is hydrogen, alkyl to C25, aryl, or R, n is 1 to 4, and the number of olefinic groups in Y is at least 3 when each Y is and otherwise is at least 2. Photosensitive polyamic acids and polyimides can be prepared from the aromatic diamines which can be crosslinked with light to a mask to form patterns on a substrate.
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- Process for the preparation of perylene-3,4,9,10-tetracarboxylic dianhydride
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Process for the preparation of perylene-3,4,9,10-tetracarboxylic dianhydride of high purity and in a very good yield in an ecologically unobjectionable manner, which comprises saponifying perylene-3,4,9,10-tetracarboxylic acid diimide with a 2.5-fold to 6-fold amount by weight of 92.5% to 97.5% strength sulfuric acid at temperatures of 210° to 230° C., washing the resulting mixture of perylene-3,4,9,10-tetracarboxylic dianhydride and perylene-3,4,9,10-tetracarboxylic acid monoanhydride-monoimide with a 0-fold to 4-fold amount by weight of 80-95% strength sulfuric acid, and then washing it with water until it is neutral, converting the compounds present in the mixture into their potassium salts by means of potassium hydroxide, after removing the perylene-3,4,9,10-tetracarboxylic acid monoanhydride-monoimide, adding to the solution of the tetrapotassium salt of perylene-3,4,9,10-tetracarboxylic acid, under nitrogen and with the exclusion of air and light, a salt of iron, nickel, calcium, magnesium, aluminum, tin, copper, lead, zinc or manganese, suspended or dissolved in water, and allowing this salt to act at a pH>10 and at temperatures from 0° to 100° C., then clarifying the mixture and converting the tetrapotassium salt of perylene-3,4,9,10-tetracarboxylic acid by acidification into perylene-3,4,9,10-tetracarboxylic dianhydride and isolating the latter in a customary manner.
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- DERIVATIVES OF 1,1'-BINAPHTHYL. IX. FORMATION OF DERIVATIVES OF 3,4,9,10-PERYLENETETRACARBOXYLIC ACID BY ELECTROCHEMICAL REDUCTION OF 8,8'-DISUBSTITUTED DERIVATIVES OF 1,1'-BINAPHTHYL-4,4',5,5'-TETRACARBOXYLIC ACID
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The electrochemical reduction of 1,1'-binaphthyl-4,4',5,5'-tetracarboxylic dianhydride, N,N'-diphenyl-1,1'-binaphthyl-4,4',5,5'-tetracarboxydiimide and its 8,8'-dicarboxymethyl derivative, the dianhydride, diimide, and N,N'-diphenyldiimide of 1,1'-binaphthyl-4,4',5,5',8,8'-hexacarboxylic acid, and the N-phenylimide of 1,1'-binaphthyl-4,4',5,5',8,8'-hexacarboxylic monoanhydride in dimethylformamide was studied by polarography, electrosynthesis, and ESR spectroscopy.The corresponding derivatives of 3,4,9,10-perylenetetracarboxylic acid were formed.The radical anion of the carboxylate ion of the initial compound enters into the cyclization of the 1,1'-binaphthyl-4,4',5,5',8,8'-hexacarboxylic acid derivatives.It is suggested, that the cyclization takes place with the initial formation of a bond between the carbon atoms at positin 8 and 8' with subsequent elimination of the substituents.
- Vorozhtsov, G.N.,Ryabinin, V.A.,Starichenko, V.F.,Shein, S.M.
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p. 887 - 894
(2007/10/02)
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- Synthesis and Reactions of Perylenecarboxylic Acid Derivatives. VII. Hydrolysis of N,N'-Dialkyl-3,4:9,10-Perylenebis(dicarboximide) with Sulfuric Acid
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The hydrolysis of N,N'-dialkyl-3,4:9,10-perylenebis(dicarboximide) (alkyl = CH3, CH2CH3, CH2CH2CH3, and CH2CH2CH2CH3) with sulfuric acid at 180 - 200 deg C gave N-alkyl-3,4:9,10-perylenetetracarboxylic monoanhydride monoimide (alkyl = CH3, CH2CH3, CH2CH2CH3, and CH2CH2CH2CH3).The kinetics of the reaction were determined spectroscopically.
- Nagao, Yukinori,Misono, Takahisa
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p. 1269 - 1270
(2007/10/02)
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