128-69-8

Basic information

• Product Name: 3,4,9,10-Perylenetetracarboxylic dianhydride
• Synonyms: 3,4,9,10-PERYLENETETRACARBOXYLIC DIANHYDRIDE;PIGMENT RED 224;PERYLENE-3,4,9,10-TETRACARBOXYLIC DIANHYDRIDE;PERYLENETETRACARBOXYLIC ACID(-3,4,9,10)-DIANHYDRIDE;1,3,8,10-Tetraoxaperylo[3,4-cd:9,10-cd]dipyran;3,4,9,10-Perylenetetracarboxylicacidanhydride;3,4:9,10-Perylenetetracarboxylic anhydride;Perylene-3,4,9,10-tetracarboxylic 3,4:9,10-dianhydride
• CAS NO: 128-69-8
• Molecular Formula: C24H8O6
• Molecular Weight: 392.32
• EINECS: 204-905-3
• Product Categories: Intermediates of Dyes and Pigments;Aromatic Hydrocarbons (substituted) & Derivatives;Organics;Acid Anhydrides, etc. (Reagents for Conducting Polymer Research);Aromatic Tetracarboxylic Dianhydrides (for High-Performance Polymer Research);Electroluminescence;Functional Materials;Reagent for High-Performance Polymer Research;Reagents for Conducting Polymer Research
• Mol File: 128-69-8.mol
• Article Data: 15

Chemical Properties

• Melting Point: >300 °C(lit.)
• Boiling Point: 477.07°C (rough estimate)
• Flash Point: 329.9 °C
• Appearance: Dark red/Powder
• Density: 1.3306 (rough estimate)
• Refractive Index: 1.5200 (estimate)
• Storage Temp.: Store below +30°C.
• Solubility: 0.87g/l
• Water Solubility: insoluble
• Sensitive: Moisture Sensitive
• BRN: 57831
• CAS DataBase Reference: 3,4,9,10-Perylenetetracarboxylic dianhydride(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,9,10-Perylenetetracarboxylic dianhydride(128-69-8)
• EPA Substance Registry System: 3,4,9,10-Perylenetetracarboxylic dianhydride(128-69-8)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• F: 10-21
• TSCA: Yes
• Hazardous Substances Data: 128-69-8(Hazardous Substances Data)

Usage

Chemical Properties

dark red powder

Uses

3,4,9,10-Perylenetetracarboxylic dianhydride is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is mainly used in air dried and baking enamels, epoxy, polyurethane and polyester based paints. It is also used in printing inks for bank and security documents.

General Description

Perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA) is a perylene derivative which forms highly crystalline films and dyes that can be used for a majority of electronic and opto-electronic applications. It provides a high electron mobility due to its low intermolecular distance which results in π-π conjugation.

Flammability and Explosibility

Notclassified

InChI:InChI=1/C48H22O15/c49-41(50)25-15-13-21-19-9-1-5-17-7-3-11-23(27(17)19)31-29(21)33(25)35(43(53)54)37(45(57)58)39(31)47(61)63-48(62)40-32-24-12-4-8-18-6-2-10-20(28(18)24)22-14-16-26(42(51)52)34(30(22)32)36(44(55)56)38(40)46(59)60/h1-16H,(H,49,50)(H,51,52)(H,53,54)(H,55,56)(H,57,58)(H,59,60)

Synthetic route

N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide (110590-84-6) → N-(1-hexylheptyl)-perylene-3,4,9,10-tetracarboxylic-3,4-carboximide-9,10-anhydride (130296-37-6) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8)

Conditions	Yield
With potassium hydroxide In tert-butyl alcohol for 0.166667h; Heating;	A 63% B n/a
With potassium hydroxide In tert-butyl alcohol Heating;	A 40% B n/a

N,N'-bis(1-octylnonyl)-perylene-3,4,9,10-tetracarboxylic diimide (139260-31-4) → perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + N-(1-octylnonyl)-perylene-3,4:9,10-tetracarboxylic acid-3,4-anhydride-9,10-carboximide (162109-59-3)

Conditions	Yield
With potassium hydroxide In tert-butyl alcohol Heating;	A n/a B 58%

1,1'-binaphthyl-4,4',5,5',8,8'-hexacarboxylic acid dianhydride sodium salt (82718-41-0) → 1,1'-binaphthyl-4,4',5,5',8,8'-hexacarboxylic acid dianhydride disodium salt (82718-41-0) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8)

Conditions	Yield
Product distribution; Mechanism; electrolysis at -1.0 V;	A n/a B 55%

N,N’-bis-(10-nonadecyl)perylene-3,4,9,10-tetracarboxylic acid diimide (130296-48-9) → 9-(1-nonyldecyl)-1H-isochromeno[6',5',4':10,5,6]anthra[2,1,9-def]isoquinoline-1,3,8,10(9H)-tetraone (130296-39-8) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8)

Conditions	Yield
With potassium hydroxide In tert-butyl alcohol Heating;	A 50.1% B n/a

1,1'-binaphthyl-4,4',5,5'-tetracarboxylic acid dianhydride (38687-17-1) → perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8)

Conditions	Yield
Product distribution; Mechanism; electrolysis at -1.3 V;	3%

perylene-3,4,9,10-tetracarboxylic acid (81-32-3) → perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8)

Conditions	Yield
With acetic anhydride
With sodium hydroxide
With sulfuric acid at 20℃; for 12h;

acenaphthylene (208-96-8) → perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8)

Conditions	Yield
Multi-step reaction with 4 steps 1.1: acetic acid; potassium dichromate / 6 h / 80 °C 2.1: ammonium hydroxide / 1.67 h / 20 - 70 °C 3.1: barium(II) hydroxide; sodium acetate / 6 h / 200 - 300 °C / Inert atmosphere 3.2: 1 h / 75 °C 3.3: 1.5 h / 80 - 100 °C 4.1: sulfuric acid / 2 h / 220 °C 4.2: 1 h / 90 °C / Darkness; Inert atmosphere View Scheme
Multi-step reaction with 4 steps 1: acetic acid / 6 h / 20 - 80 °C 2: ammonium hydroxide / 1.67 h / 20 - 70 °C 3: potassium hydroxide; sodium acetate / dimethyl sulfoxide / 6 h / 100 °C / Microwave irradiation; Inert atmosphere 4: sulfuric acid / 2 h / 220 °C View Scheme

1,8-Naphthalic anhydride (81-84-5) → perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8)

Conditions	Yield
Multi-step reaction with 3 steps 1.1: ammonium hydroxide / 1.67 h / 20 - 70 °C 2.1: barium(II) hydroxide; sodium acetate / 6 h / 200 - 300 °C / Inert atmosphere 2.2: 1 h / 75 °C 2.3: 1.5 h / 80 - 100 °C 3.1: sulfuric acid / 2 h / 220 °C 3.2: 1 h / 90 °C / Darkness; Inert atmosphere View Scheme
Multi-step reaction with 3 steps 1: ammonium hydroxide / 1.67 h / 20 - 70 °C 2: barium(II) hydroxide; sodium acetate / 6 h / 200 - 300 °C / Inert atmosphere 3: sulfuric acid / 2 h / 20 - 220 °C View Scheme
Multi-step reaction with 3 steps 1: ammonium hydroxide / 1.67 h / 20 - 70 °C 2: potassium hydroxide; sodium acetate / dimethyl sulfoxide / 6 h / 100 °C / Microwave irradiation; Inert atmosphere 3: sulfuric acid / 2 h / 220 °C View Scheme

1,8-Naphthalimide (81-83-4) → perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8)

Conditions	Yield
Multi-step reaction with 2 steps 1.1: barium(II) hydroxide; sodium acetate / 6 h / 200 - 300 °C / Inert atmosphere 1.2: 1 h / 75 °C 1.3: 1.5 h / 80 - 100 °C 2.1: sulfuric acid / 2 h / 220 °C 2.2: 1 h / 90 °C / Darkness; Inert atmosphere View Scheme
Multi-step reaction with 2 steps 1: barium(II) hydroxide; sodium acetate / 6 h / 200 - 300 °C / Inert atmosphere 2: sulfuric acid / 2 h / 20 - 220 °C View Scheme
Multi-step reaction with 2 steps 1: potassium hydroxide; sodium acetate / dimethyl sulfoxide / 6 h / 100 °C / Microwave irradiation; Inert atmosphere 2: sulfuric acid / 2 h / 220 °C View Scheme

acenaphthene (83-32-9) → perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8)

Conditions	Yield
Multi-step reaction with 4 steps 1: acetic acid; potassium dichromate / 6 h / 20 - 80 °C 2: ammonium hydroxide / 1.67 h / 20 - 70 °C 3: barium(II) hydroxide; sodium acetate / 6 h / 200 - 300 °C / Inert atmosphere 4: sulfuric acid / 2 h / 20 - 220 °C View Scheme

1-hexylheptylamine (22513-16-2) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide (110590-84-6)

Conditions	Yield
With 1H-imidazole at 180℃; for 5h;	100%
With 1H-imidazole In dichloromethane at 150℃; for 5h;	100%
With 1H-imidazole; zinc diacetate at 155℃; for 4h;	99%

1-pentanamine (110-58-7) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N’-bis(pentyl)-3,4:9,10-perylenebis(dicarboximide) (76372-75-3)

Conditions	Yield
In N,N-dimethyl-formamide for 4h; Reflux;	100%
With 1H-imidazole for 1h;	96%
In 1H-imidazole at 160℃; for 1h; Autoclave;
With zinc acetate hydrate In quinoline Reflux;
Stage #1: n-Pentylamine; perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride In water at 20℃; for 0.333333h; Green chemistry; Stage #2: In water at 200℃; for 24h; Autoclave; High pressure; Green chemistry;

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + 1-aminooctadecane (124-30-1) → N,N’-bis(octadecyl)-3,4:9,10-perylenebis(dicarboximide) (25834-02-0)

Conditions	Yield
In N,N-dimethyl-formamide for 8h; Reflux;	100%
With 1H-imidazole at 140℃; for 3h;	89%
	63%

L-leucine (61-90-5) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N'-bis((S)-1-carboxy-3-methylbutyl)-3,4:9,10-perylenetetracarboxylic diimide

Conditions	Yield
With 1H-imidazole at 100℃; for 1h; Inert atmosphere;	100%
With 1H-imidazole at 120℃; for 0.5h;	97%
With 1H-imidazole at 120℃;	95.4%

1-dodecylbromide (143-15-7) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → tetradodecyl perylene-3,4,9,10-tetracarboxylate

Conditions	Yield
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With potassium hydroxide In water Stage #2: 1-dodecylbromide With potassium iodide	100%
With Aliquat 336; potassium iodide; potassium hydroxide Inert atmosphere;	96%
With 1-dodecyl alcohol; 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 60℃; for 12h;	86%

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → perylene-3,4,9,10-tetracarboxylic acid monoanhydride monopotassium carboxylate (79915-95-0)

Conditions	Yield
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With potassium hydroxide In water for 2h; Stage #2: With acetic acid In water at 90℃; for 0.666667h;	99%
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With potassium hydroxide at 90℃; for 1h; Stage #2: With phosphoric acid	96%
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With water; potassium hydroxide at 90℃; for 2h; Stage #2: With acetic acid at 90℃; for 0.666667h;	96%

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → 1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride (118129-60-5)

Conditions	Yield
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With sulfuric acid; iodine at 20 - 85℃; for 0.75h; Stage #2: With bromine at 95℃;	99%
With sulfuric acid; bromine at 40℃; for 12h;	95%
With sulfuric acid; iodine	95%

2-Ethylhexylamine (104-75-6) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → 2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d',e',f']diisoquinoline-1,3,8,10(2H,9H)-tetraone (82531-03-1)

Conditions	Yield
With 1H-imidazole; zinc diacetate at 160℃; for 5h; Inert atmosphere;	99%
With 1H-imidazole	98%
In N,N-dimethyl-formamide for 8h; Inert atmosphere; Reflux;	97%

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride (156028-26-1)

Conditions	Yield
With sulfuric acid; chlorine at 120℃;	99%
With chlorosulfonic acid; iodine at 65℃; for 20h;	98%
With chlorosulfonic acid; iodine at 65℃; for 20h;	94%

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → perylene-3,4,9,10-tetracarboxylic acid (81-32-3)

Conditions	Yield
With potassium hydroxide In water for 12h; Heating;	99%
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With potassium hydroxide In water at 20℃; for 6h; Stage #2: With hydrogenchloride In water pH=Ca. 7;	80%
With sodium hydroxide

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + N,N-dimethylethylenediamine (108-00-9) → 2,9-bis(2-(dimethylamino)ethyl)anthra[2,1,9-def:6,5,10-d′e′f ′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone (73528-89-9)

Conditions	Yield
In N,N-dimethyl-formamide at 200℃; for 0.966667h; Microwave irradiation;	99%
In iso-butanol at 90℃; for 24h; Inert atmosphere;	97%
In N,N-dimethyl-formamide at 130℃; for 5h;	92%

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + 2-(2-Aminoethoxy)ethanol (929-06-6) → 2,9-bis(2-(2-hydroxyethoxy)ethyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone (238755-74-3)

Conditions	Yield
In N,N-dimethyl-formamide at 200℃; for 0.966667h; Microwave irradiation;	99%
at 130℃; for 3h;	94%
at 130℃; for 3h; Inert atmosphere;
With N,N-dimethyl acetamide; zinc diacetate at 160℃; for 8h; Inert atmosphere;

2-n-hexyldecan-1-amine (62281-05-4) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N'-di(2-n-hexyldecyl)-perylene-3,4:9,10-tetracarboxylic acid bisimide (1331760-59-8)

Conditions	Yield
With 1H-imidazole; zinc diacetate at 160℃; Inert atmosphere;	99%
With 1H-imidazole at 180℃; for 4h; Inert atmosphere;	86%
With 1H-imidazole at 160℃; for 5h; Inert atmosphere;	71%

2-butyloctan-1-amine + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N;-bis(2-butyloctyl)-3,4,9,10-perylene diimide (1331760-57-6)

Conditions	Yield
With 1H-imidazole; zinc diacetate at 160℃; Inert atmosphere;	99%

3-(1H-imidazol-1-yl)propan-1-amine (5036-48-6) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → 2,9-bis(3-(1H-imidazol-1-yl)propyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone

Conditions	Yield
In N,N-dimethyl-formamide at 200℃; for 0.966667h; Microwave irradiation;	99%
In N,N-dimethyl-formamide at 140℃; for 72h;	95%
In N,N-dimethyl-formamide at 140℃;	92.3%
In 2-methyl-propan-1-ol at 90℃;

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + 2-methoxyethylamine (109-85-3) → 2,9-bis(2-methoxyethyl)anthra[2,1,9-def:6,5,10-d'e'f']-diisoquinoline-1,3,8,10(2H,9H)-tetraone (59765-31-0)

Conditions	Yield
In N,N-dimethyl-formamide at 200℃; for 0.966667h; Microwave irradiation;	99%

C30H56N4O4S + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → C84H112N8O10S2

Conditions	Yield
With 1H-imidazole In water at 145 - 180℃; for 15h; Inert atmosphere;	99%

1-bromo-butane (109-65-9) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → perylene-3,4:9,10-tetra(n-butoxy)tetracarboxylic acid tetraester

Conditions	Yield
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With water; potassium hydroxide at 70℃; for 1.5h; Stage #2: 1-bromo-butane With Aliquat 336 at 100℃; for 2h; pH=9;	98.1%
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With potassium hydroxide In water at 75℃; for 1.5h; Stage #2: 1-bromo-butane In water at 100℃; for 2h;	94.8%
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With potassium hydroxide In water at 75℃; for 1.5h; Stage #2: 1-bromo-butane With tetrabutylammomium bromide at 100℃; for 2h;	94.8%

cyclohexylamine (108-91-8) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide (41572-86-5)

Conditions	Yield
at 135℃; for 24h;	98%
for 15h; Reflux;	93%
at 140℃; for 15h;	93%

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + 3-aminopentane (616-24-0) → N,N'-bis(1-ethylpropyl)-3,4:9,10-perylenebis(dicarboximide) (110590-81-3)

Conditions	Yield
With 1H-imidazole at 110℃; for 24h;	98%
With 1H-imidazole at 140℃; for 5h; Inert atmosphere;	96%
With 1H-imidazole at 200℃; for 2h;	92%

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + 1-amino-2-propene (107-11-9) → N,N'-diallylperylene-3,4:9,10-tetracarboxylic acid bisimide (110590-73-3)

Conditions	Yield
With zinc diacetate In quinoline at 120℃; for 5h;	98%
With 1H-imidazole at 160℃; for 4h;	42%
With zinc diacetate In quinoline at 120℃; for 5h;

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + methylamine (74-89-5) → N,N'-Dimethylperylene-3,4,9,10-biscarboximide (5521-31-3)

Conditions	Yield
In water for 3h; Heating;	98%

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → 1,7-dinitro-3,4,9,10-perylenetetracarboxylic acid (74616-86-7)

Conditions	Yield
With nitric acid In chloroform at 25 - 30℃; for 2.5h;	98%

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + N,N-diethylethylenediamine (100-36-7) → N,N'-bis(2-(N'',N''-diethylamino)ethyl)perylene-3,4:9,10-bis(dicarboximide) (73528-90-2)

Conditions	Yield
for 26h; Reflux;	98%
In N,N-dimethyl-formamide at 80℃; Inert atmosphere;	85%
at 100℃; for 15h;

2-octyldodecylamine (62281-06-5) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N'-bis(2-octyldodecyl)-perylene-3,4,9,10-bis(dicarboxiamide)

Conditions	Yield
With 1H-imidazole; zinc diacetate at 160℃; Inert atmosphere;	98%
With 1H-imidazole In o-xylene at 180℃; for 4h; Inert atmosphere;	93.2%
With 1H-imidazole In o-xylene at 180℃; for 4h; Inert atmosphere;	93%

1-bromo-butane (109-65-9) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + butan-1-ol (71-36-3) → perylene-3,4:9,10-tetra(n-butoxy)tetracarboxylic acid tetraester

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile for 18h; Reflux;	98%
With tetra(n-butyl)ammonium hydroxide; potassium carbonate In water at 120℃; for 2h; Time; Inert atmosphere;	97%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 100℃; for 2h;	93%

3-(3,5,7,9,11,13,15-heptaisobutylpentacyclo[9,5,1,1(3,9),1(7,13),1(5,15)]octasiloxane-1-yl)propylamine (444315-15-5) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N'-propylheptakis(isobutyl) POSS-perylene tetracarboxylic acid bisimide (1005347-68-1)

Conditions	Yield
With 1H-imidazole for 0.0833333h; Microwave irradiation;	98%
With 1H-imidazole at 120 - 140℃; for 4h;	95%
With 1H-imidazole at 140℃; for 4h;	95%

Upstream product

• 208-96-8 acenaphthylene 
• 81-84-5 1,8-Naphthalic anhydride 
• 81-83-4 1,8-Naphthalimide 
• 83-32-9 acenaphthene 
• 81-33-4 3,4,9,10-perylene tetracarboxyxlic acid diimide 
• 7783-06-4 hydrogen sulfide 
• 110590-81-3 N,N'-bis(1-ethylpropyl)-3,4:9,10-perylenebis(dicarboximide) 
• 139260-31-4 N,N'-bis(1-octylnonyl)-perylene-3,4,9,10-tetracarboxylic diimide 
• 130296-48-9 N,N’-bis-(10-nonadecyl)perylene-3,4,9,10-tetracarboxylic acid diimide 
• 110590-84-6 N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide 
• 59442-38-5 N,N’-bis(propyl)perylene-3,4,9,10-bis(dicarboximide) 
• 59385-83-0 N,N’-bis(ethyl)perylene-3,4,9,10-bis(dicarboximide) 
• 52000-75-6 N¹,N²-bis(1-butyl)perylene-3,4,9,10-tetracarboxylic diimide 
• 82718-41-0 1,1'-binaphthyl-4,4',5,5',8,8'-hexacarboxylic acid dianhydride sodium salt 

Downstream Products

• 118129-60-5 1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride 
• 331861-94-0 1,7-dibromo-N,N'-bis(2,6-diisopropylphenyl)perylene-3,4:9,10-tetracarboxylic acid diimide 
• 578764-59-7 (S,S)-N,N'-bis{1-[6-(4-bromophenoxy)hexyloxy]methyl-3-methylbutyl}perylene 3,4:9,10-perylenetetracarboxylicbisimide 
• 578764-63-3 (S,S)-N,N'-bis[1-(4-bromophenoxymethyl)-3-methylbutyl]perylene-3,4:9,10-tetracarboxylicbisimide 
• 165261-25-6 N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide 
• 83054-80-2 N,N'-bis(2,5-di-tert-butylphenyl)perylene-3,4:9,10-bis(dicarboximide) 
• 67075-37-0 anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetrone,2,9-bis(2-phenylethyl) 
• 198-55-0 PERYLENE 
• 139260-31-4 N,N'-bis(1-octylnonyl)-perylene-3,4,9,10-tetracarboxylic diimide 
• 110590-84-6 N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide 
• 165261-27-8 2-(1-hexylheptyl)-1H-benzo-[5,10]anthra[2,1,9-def ]isoquinolin-1,3(2H)-dione 

Related news

Synthesis of tube shape MnO/Cp composite from 3,4,9,10-Perylenetetracarboxylic dianhydride (cas 128-69-8) for lithium ion batteries09/30/2019

The composite of MnO and carbon pyrolysis from PTCDA (named as MnO/Cp) has been synthesized via a facile adsorption of Mn2+ on 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA), followed by thermal annealing process. PTCDA is employed as a precursor of carbon and forms a tube shape via calcin...detailed

Tunneling spectroscopy study of 3,4,9,10-Perylenetetracarboxylic dianhydride (cas 128-69-8) on Au(100)09/28/2019

The organic molecule 3,4,9,10-perylenetetracarboxylic-3,4,9,10-dianhydride (PTCDA) deposited on Au(100) has been investigated by scanning tunneling spectroscopy (STS). For this purpose, highly ordered ultrathin PTCDA films have been prepared by organic molecular beam epitaxy. Single point curren...detailed

Structural and Morphological Properties of 3,4,9,10-Perylenetetracarboxylic dianhydride (cas 128-69-8) Films on Passivated GaAs(100) Substrates09/26/2019

Raman spectroscopy is employed to investigate in situ the structural properties and the morphology of 3,4,9,10-Perylene-TetraCarboxylic DiAnhydride (PTCDA) films deposited onto S-GaAs(100) substrates at various temperatures. Additional two-dimensional Raman mapping measurements are carried out e...detailed

Spectroscopic ellipsometry of 3,4,9,10-Perylenetetracarboxylic dianhydride (cas 128-69-8) (PTCDA)09/25/2019

The optical functions of PTCDA have been determined by spectroscopic ellipsometry. The samples were prepared by thermal evaporation of PTCDA on glass substrates. The influence of the substrate temperature on the properties of PTCDA films has also been investigated. The lowest substrate temperatu...detailed

Relevant articles and documents

Inorganic/organic small molecular semiconductor self-assembly to functional core-shell nanoarchitectures for ultrasensitive chemiresistors to aniline vapor

We developed a new method combining the in situ liquid-solid phase reaction and self-assembly in solution to synthesize novel inorganic/organic small molecular semiconductor core-shell nanoparticles of ZnS/PTCDA (ZPNPs). This method is a one-step process which can produce stoichiometric inorganic/organic core-shell nanoparticles and does not introduce any impurity. The film of ZPNPs exhibited an ultrasensitive detection of aniline vapor. The film of ZPNPs can highly selectively distinguish aniline vapor from many volatile organic compounds and water due to the strong synergistic interactions of π-π and hydrogen-bonds between electron donor (aniline) and acceptor (PTCDA) molecules, in which the detection limit was lowered to 100 ppb at room temperature. This journal is the Partner Organisations 2014.

Preparation method and application of novel perylene drug molecule with biological activity

The invention discloses a preparation method and application of a novel perylene drug molecule with the biological activity, and belongs to the technical field of medicine synthesis. According to thekey points of the technical scheme of the preparation method and application of the novel perylene drug molecule, the structural formula of the perylene drug molecule with the biological activity is as shown in the specification, wherein R is O or S. The invention further relates to the preparation method for the novel perylene drug molecule with the biological activity. The perylene drug moleculeprepared through the preparation method has good inhibitory activity on human cervical cancer hHela cells, human breast cancer MDA-MB-231 cells and human liver cancer HepG2 cells, is relatively low in toxicity on human normal cells and has the potential of becoming an anti-tumor drug.

Preparation method of Lumogen Red F300

The invention relates to Lumogen Red F300, in particular to a preparation method of the Lumogen Red F300. The preparation method comprises the following steps that 1,6,7,12-tetrabromo-3,4,9,10-perylenetetracarboxylic dianhydride is prepared; a 1,6,7,12-tetraphenoxy-3,4,9,10-perylenetetracarboxylic potassium aqueous solution is prepared; and an amination reaction is performed. The preparation method is more scientific and reasonable; and the color fastness is relatively higher, so that the Lumogen Red F300 is close to functional dye.