Electrophile Induced Reactions of Medium Ring Vinyl- and 1,2-Epoxy-silanes and Related Compounds
Deuterium labelling studies confirm extensive trans-annular participation in acidolysis, acetylation and brominolysis of 1,2-epoxy-1-trimethylsilylcyclooctane and (E)-1-trimethylsilylcyclooctene, and require revision of previous mechanistic proposals.
Wells, Adam P.,Riches, Bruce H.,Kitching, William
p. 1575 - 1577
(2007/10/02)
A FACILE ROUTE TO BICYCLOOCTANES THROUGH CLEAN TRANSANNULAR CYCLISATION OF 1-TRIMETHYLSILYLCYCLOOCTENE UNDER FRIEDEL-CRAFTS CONDITION
A wide range of exo-cis-bicyclo-2-octyl ketones are obtained by the reaction of 1-trimethylsilylcyclooctene with various acyl chlorides in presence of aluminium chloride.
Bandodakar, Balachandra S.,Nagendrappa, Gopalpur
p. 7461 - 7462
(2007/10/02)
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