129750-61-4Relevant articles and documents
Comparison of carbon-silicon hyperconjugation at the 2- and 4-positions of the N-methylpyridinium cation
Hassall, Kathryn,Lobachevsky, Sofia,White, Jonathan M.
, p. 1993 - 1997 (2005)
(Chemical Equation Presented) N-Methyl-2-trialkylsilylmethylpyridinium cations 6a-c and 4-trialkylsilylmethylpyridinium cations 5a-c were prepared and investigated using 29Si and 13C NMR and single-crystal X-ray crystallography. Syst
Formal synthesis of Manzamine C via a sila-Cope elimination
Vidal, Thierry,Magnier, Emmanuel,Langlois, Yves
, p. 5959 - 5966 (2007/10/03)
Piperidine derivative 7, prepared in six steps from 2-methylpyridine, afforded by a sila-Cope elimination aminoalcohol 10 which is a direct synthetic precursor of the azaundecene ring of Manzamine C 2.
Synthesis of a pheromone of Boarmia selenaria via a Sila-Cope elimination. Stereochemical implications
Langlois,Konopski,Bac,Chiaroni,Riche
, p. 1865 - 1868 (2007/10/02)
The use of a Sila-Cope elimination afforded a Z,Z,Z trienamine derivative, direct synthetic precursor of (3Z,6Z,9Z)-3,6,9-nonadecatriene 1, one of the pheromone components of Boarmia selenaria. X-ray analysis of the tetrahydropyridinium salt 13 leading to