1301664-00-5Relevant academic research and scientific papers
Silver-catalyzed cycloisomerization of 1,n-allenynamides
Garcia, Pierre,Harrak, Youssef,Diab, Lisa,Cordier, Pierre,Ollivier, Cyril,Gandon, Vincent,Malacria, Max,Fensterbank, Louis,Aubert, Corinne
, p. 2952 - 2955 (2011/07/08)
A variety of allenynamides can undergo cycloisomerization reactions in the presence of silver triflate thus leading to the formation of N-containing heterocycles incorporating cross-conjugated trienes. Access to new dienic 4-piperidinone and azepane motifs was achieved. An extension to one-pot tandem sequences involving silver-catalyzed cycloisomerization/Diels-Alder reaction was also examined.
