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2-METHYL-1-DECENE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

13151-27-4

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13151-27-4 Usage

Synthesis Reference(s)

Tetrahedron Letters, 29, p. 1811, 1988 DOI: 10.1016/S0040-4039(00)82050-X

Check Digit Verification of cas no

The CAS Registry Mumber 13151-27-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,1,5 and 1 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 13151-27:
(7*1)+(6*3)+(5*1)+(4*5)+(3*1)+(2*2)+(1*7)=64
64 % 10 = 4
So 13151-27-4 is a valid CAS Registry Number.
InChI:InChI=1/C11H22/c1-4-5-6-7-8-9-10-11(2)3/h2,4-10H2,1,3H3

13151-27-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-methyldec-1-ene

1.2 Other means of identification

Product number -
Other names 1-Decene,2-methyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13151-27-4 SDS

13151-27-4Relevant articles and documents

Zirconocene-catalyzed alkylative dimerization of 2-methylene-1,3-dithiane via a single electron transfer process to provide symmetrical vic-bis(dithiane)s

Yoshida, Suguru,Yorimitsu, Hideki,Oshima, Koichiro

, p. 3110 - 3114 (2007)

A mixture of tertiary alkyl halide and 2-methylene-1,3-dithiane was treated with butylmagnesium bromide in the presence of a catalytic amount of zirconocene dichloride. The reaction resulted in alkylative dimerization to yield the corresponding vic-bis(dithiane). The reaction would proceed as follows. A single electron transfer from low-valent zirconocene to alkyl halide would generate the corresponding alkyl radical. The radical adds to 2-methylene-1,3-dithiane to afford the corresponding radical stabilized by the two sulfur atoms. A couple of the stable radicals finally undergo dimerization.

Silver-catalyzed benzylation and allylation of tertiary alkyl bromides with organozinc reagents

Mitamura, Yukihiro,Asada, Yoshihiro,Murakami, Kei,Someya, Hidenori,Yorimitsu, Hideki,Oshima, Koichiro

experimental part, p. 1487 - 1493 (2011/07/07)

Silver salts catalyze the benzylation and allylation of tertiary alkyl bromides with organozinc reagents. The reactions create quaternary carbon centers efficiently. Treatment of gem-dibromoalkanes with benzylic or allylic zinc reagents under silver catalysis leads to dibenzylation or diallylation. The functional-group compatibility of the present reactions is wider than that of the previous reactions with Grignard reagents.

THE TITANOCENE METHYLENE-ZINC HALIDE COMPLEX: A CONVENIENT SYNTHESIS AND ITS METHYLENATING ACTION ON UNSATURATED CARBON CENTERS

Eisch, John J.,Piotrowski, Andrzej

, p. 2043 - 2046 (2007/10/02)

The titanocene methylene-zinc halide complex, which can be conveniently prepared by treating titanocene dichloride with methylenezinc iodide in THF solution, readily methylenates ketones, nitriles, and alkynes.

New Synthesis of Cyclopropanes from 1,3-Dicarbonyl Compounds Utilizing Electroreduction of 1,3-Dimethanesulfonates

Shono, Tatsuyo,Matsumura, Yoshihiro,Tsubata, Kenji,Sugihara, Yoshihiro

, p. 3090 - 3094 (2007/10/02)

Electroorganic synthesis of cyclopropanes from dimethanesulfonates of 1,3-diols is described.The process involves reduction of 1,3-dicarbonyl compounds with LiAlH followed by esterification with methanesulfonyl chloride and electroreduction.

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