2-METHYL-1-DECENE

Base Information

• Chemical Name: 2-METHYL-1-DECENE
• CAS No.: 13151-27-4
• Molecular Formula: C11H22
• Molecular Weight: 154.296
• Hs Code.: 2901299090
• Mol file: 13151-27-4.mol

Synonyms:2-Methyl-dec-1-en;2-Methyl-1-decene;2-methyl-dec-1-ene;1-Decene,2-methyl;

Chemical Property of 2-METHYL-1-DECENE

Chemical Property:

• Vapor Pressure: 0.831mmHg at 25°C
• Melting Point: -51.48°C
• Refractive Index: 1.4263
• Boiling Point: 188.3oC at 760 mmHg
• Flash Point: 57.7oC
• PSA: 0.00000
• Density: 0.752g/cm3
• LogP: 4.31310

Purity/Quality:

97% ^*data from raw suppliers

2-Methyl-1-decene 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-METHYL-1-DECENE

There total 4 articles about 2-METHYL-1-DECENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Methanesulfonic acid 2-methanesulfonyloxymethyl-decyl ester (64923-67-7) → 2-methyl-dec-1-ene (13151-27-4) + n-octylcyclopropane (1472-09-9)

Guidance literature:

With tetraethylammonium tosylate; In N,N-dimethyl-formamide; electrochemical reduction;

DOI:10.1021/jo00137a012

Reference yield: 48.0%

benzylzinc chloride-lithium chloride complex + 2-methyl-2-bromodecane (502760-08-9) → 2-methyl-2-decene (23381-92-2) + 2-methyl-dec-1-ene (13151-27-4) + 2,2-dimethyl-1-phenyldecane (67969-62-4)

Guidance literature:

With silver trifluoromethanesulfonate; In acetonitrile; at 25 ℃; for 3h; Inert atmosphere;

DOI:10.1002/asia.201000068

Reference yield: 45.0%

1-decyne (764-93-2) → 2-methyl-dec-1-ene (13151-27-4) + 1-undecene (821-95-4) + 9,12-Dimethylene-icosane (87368-01-2)

Guidance literature:

Yield given. Yields of byproduct given;

DOI:10.1016/S0040-4039(00)81839-0

upstream raw materials:

Methanesulfonic acid 2-methanesulfonyloxymethyl-decyl ester

1-decyne

n-butyl magnesium bromide

t-butyl bromide

Downstream raw materials:

2-methyl-2-phenyl-decane

2-methyldecane

2-methyl-2-decene

2-methyldecan-2-ol

Refernces

• 1、 Mitamura, Yukihiro,Asada, Yoshihiro,Murakami, Kei,Someya, Hidenori,Yorimitsu, Hideki,Oshima, Koichiro. "Silver-catalyzed benzylation and allylation of tertiary alkyl bromides with organozinc reagents". experimental part. p. 1487 - 1493. Retrieved 2011/07/07.
• 2、 Shono, Tatsuyo,Matsumura, Yoshihiro,Tsubata, Kenji,Sugihara, Yoshihiro. "New Synthesis of Cyclopropanes from 1,3-Dicarbonyl Compounds Utilizing Electroreduction of 1,3-Dimethanesulfonates". . p. 3090 - 3094. Retrieved 2007/10/02.