13154-31-9

Basic information

• Product Name: 2-NITROCYCLODODECANONE
• Synonyms: 2-NITROCYCLODODECANONE
• CAS NO: 13154-31-9
• Molecular Formula: C₁₂H₂₁NO₃
• Molecular Weight: 227.3
• Product Categories: C11 to C12;Carbonyl Compounds;Ketones
• Mol File: 13154-31-9.mol

Chemical Properties

• Melting Point: 77-80 °C(lit.)
• Boiling Point: 366.2 °C at 760 mmHg
• Flash Point: 164.1 °C
• Appearance: /
• Density: 1.04g/cm³
• Vapor Pressure: 1.48E-05mmHg at 25°C
• Refractive Index: 1.477
• CAS DataBase Reference: 2-NITROCYCLODODECANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-NITROCYCLODODECANONE(13154-31-9)
• EPA Substance Registry System: 2-NITROCYCLODODECANONE(13154-31-9)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 13154-31-9(Hazardous Substances Data)

Usage

Uses

Used in Fuel Industry:
2-NITROCYCLODODECANONE is used as a fuel additive to enhance the performance and efficiency of fuels. Its properties contribute to improved combustion and reduced emissions, making it a valuable component in the formulation of various fuel types.
Used in Chemical Production:
In the chemical industry, 2-NITROCYCLODODECANONE serves as a key intermediate in the synthesis of a wide range of chemical compounds. Its unique structure and reactivity make it a versatile building block for the creation of various products, including pharmaceuticals, agrochemicals, and specialty chemicals.

InChI:InChI=1/C12H21NO3/c14-12-10-8-6-4-2-1-3-5-7-9-11(12)13(15)16/h11H,1-10H2

Upstream product

• 71365-98-5 1-Acetoxy-cis-cyclododecen 
• 1129-89-1 cis-cyclododecene 
• 32399-66-9 Essigsaeure-(1-cyclododecenyl)ester 
• 830-13-7 cyclododecanone 

Downstream Products

• 32571-74-7 12-nitrododecanoic acid 
• 1731-79-9 dodecanedioic acid dimethyl ester 
• 52190-43-9 2-(phenylthio)cyclododecan-1-one 
• 693-23-2 1,12-dodecanedioic acid 
• 86572-33-0 benzyl 3-oxo-5-(1-nitro-2-oxocyclododecyl)pentanoate 

Relevant articles and documents

Practical and User-Friendly Procedure for Michael Reactions of α-Nitroketones in Water

A variety of α,β-unsaturated carbonyl derivatives gave selective Michael additions with several α-nitrocycloalkanones in water, at room temperature without any added catalyst, or in very dilute, aqueous solutions of potassium carbonate. Both preparative methods constitute new, environmentally benign and more efficient alternatives to previous procedures.

Unique michael addition-initiated domino reaction for the stereoselective synthesis of functionalized macrolactones from α-nitroketones in water

(Chemical Equation Presented) A unique domino reaction of α-nitrocycloalkanones with α-alkyl α,β-unsaturated aldehydes in aqueous base was discovered, leading to the one-pot synthesis of hitherto unknown functionalized, bridged, bicyclic lactones containing 10-, 11-, 13-, and 15-membered rings. The structures of these heterocyclic compounds, containing also an unusual 6-hydroxy-1,2-oxazine ring, were determined by spectral and single-crystal X-ray diffraction studies.

A novel one pot synthesis of α-nitroketones from olefins using trimethylsilylnitrate-chromium trioxide reagent system

A variety of α-nitroketones have been obtained from the corresponding olefins in good yields upon reaction with trimethylsilylnitrate-chromium trioxide reagent system.

Synthese von N-(4-Aminobutyl)-16-aza-19-nonadecanlactam und N-(4-Aminobutyl)-17-aza-20-icosanlactam (Desoxoinandenin)

According to Scheme 1, the two homologous macrocyclic spermidine derivatives 12 ad 23 were synthesized.Key steps in both cases were two different types of ring-enlargement reactions.Compound 12 was identical with a degradation product of the naturally occurring spermidine akaloids of inandine-type.