52190-43-9

Basic information

• Product Name: 2-(phenylsulfanyl)cyclododecanone
• Synonyms: 2-(Phenylthio)cyclododecanone
• CAS NO: 52190-43-9
• Molecular Formula: C₁₈H₂₆OS
• Molecular Weight: 290.4634
• Mol File: 52190-43-9.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 434.6°C at 760 mmHg
• Flash Point: 231.1°C
• Density: 1.03g/cm³
• Vapor Pressure: 9.38E-08mmHg at 25°C
• Refractive Index: 1.544
• CAS DataBase Reference: 2-(phenylsulfanyl)cyclododecanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(phenylsulfanyl)cyclododecanone(52190-43-9)
• EPA Substance Registry System: 2-(phenylsulfanyl)cyclododecanone(52190-43-9)

Safety Data

• Hazardous Substances Data: 52190-43-9(Hazardous Substances Data)

Usage

Type of compound

cyclic ketone derivative

Group attached

phenylsulfanyl group

Attachment location

on the cyclododecane ring

Potential applications

organic synthesis, material science, pharmaceuticals, agrochemicals

Versatility

suitable for use in various fields of chemistry and industry

Functionality

presence of the phenylsulfanyl group allows for further chemical modification and functionalization.

Upstream product

• 55314-44-8 [(cyclododec-1-en-1-yl)oxy](trimethyl)silane 
• 882-33-7 diphenyldisulfane 
• 830-13-7 cyclododecanone 
• 1208-20-4 S-phenyl benzenethiosulfinate 
• 31236-94-9 2-bromocyclododecan-1-one 
• 930-69-8 sodium thiophenolate 
• 1486-75-5 (E)-Cyclododecen 
• 108-98-5 thiophenol 
• 1129-89-1 cis-cyclododecene 
• 95338-32-2 2-nitrocyclododecanone 
• 931-59-9 benzenesulfenyl chloride 
• 79082-23-8 2-(phenylthio)-1-cyclododecanol 
• 28833-59-2 C₂₆H₂₄N₂O₄S₄ 
• 55314-44-8 [((E)-Cyclododec-1-enyl)oxy]-trimethyl-silane 

Downstream Products

• 63608-51-5 Acetic acid 2-oxo-1-phenylsulfanyl-cyclododecyl ester 
• 60774-63-2 2-phenylsulfinylcyclododecanone 
• 101751-38-6 (1SR,2RS)-1-methyl-2-phenylthiocyclododecanol 
• 101751-38-6 (1RS,2RS)-1-methyl-2-phenylthiocyclododecanol 
• 73465-26-6 trans-2-(Thiophenyl)-1-vinyl-1-cyclododecanol 
• 73397-74-7 cis-2-(Thiophenyl)-1-vinyl-1-cyclododecanol 
• 79082-23-8 2-(phenylthio)-1-cyclododecanol 
• 104260-90-4 2-Phenylsulfanyl-cyclododecanone oxime 
• 104281-55-2 2-Methyl-2-phenylthiocyclododecanone 
• 104281-62-1 syn-2-Methyl-2-phenylthiocyclododecanol 
• 104281-62-1 anti-2-Methyl-2-phenylthiocyclododecanol 
• 101704-24-9 1-(phenylthiomethyl)cyclododecene 
• 125334-97-6 Z-1-Methyl-12-phenylthiocyclododec-1-ene 
• 104281-68-7 E-1-Methyl-12-phenylthiocyclododec-1-ene 

Relevant articles and documents

Feasible Approach to Tricyclic and Tetracyclic cyclododecanone

2-Bromocyclododecanone was utilized as precursor to synthesize polyfused heterocyclic cyclododecane ring systems. Transformation of 2-bromocyclododecanone (5) with 1H-benzimidazole-2-thiole (6), benzo[d]thiazole-2-thiol (9), 2-naphthol (12), and thiophenol (15) afforded thiazolo[2,3-b]benzimidazole (8), thiazolo[2,3-b]benzothaizole derivative (11) naphtho[1,2-d]furan derivative (14) and 2-(phenylthio)cyclododecanone (16), respectively.

Novel chemistry of α-tosyloxy ketones: Applications to the solution- and solid-phase synthesis of privileged heterocycle and enediyne libraries

New synthetic technologies for the preparation and elaboration of α-tosyloxy ketones in solution and on solid-phase are described. Both olefins and ketones serve as precursors to these relatively stable chemical entities: olefins via a novel one-pot epoxi

New Mild Methodology for the Synthesis of α-Phenylthio and α-Phenylseleno Ketones

Treatment of trimethylsilyl enol ethers with the adduct 1, derived from chloramine-T and (PhS)2, gave good yields of α-phenylthioketones.The selenium version of this reagent 2 gave α-phenylselenoketones.