cas 131549-85-4, 4-nitrososulfamethoxazole | Articles data ｜lookchem

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131549-85-4

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Insights into the electrochemical degradation of sulfamethoxazole and its metabolite by Ti/SnO2-Sb/Er-PbO2 anode
Electrochemical degradation of sulfamethoxazole (SMX) and its metabolite acetyl-sulfamethoxazole (Ac-SMX) by Ti/SnO2-Sb/Er-PbO2 were investigated. Results indicated that the electrochemical degradation of SMX and Ac-SMX followed pseu
Wang, Yanping,Zhou, Chengzhi,Wu, Jinhua,Niu, Junfeng
supporting information
p. 2673 - 2677
(2020/06/01)

Metabolic and chemical origins of cross-reactive immunological reactions to arylamine benzenesulfonamides: T-cell responses to hydroxylamine and nitroso derivatives
Exposure to sulfamethoxazole (SMX) is associated with T-cell-mediated hypersensitivity reactions in human patients. T-cells can be stimulated by the putative metabolite nitroso SMX, which binds irreversibly to protein. The hydroxylamine and nitroso deriva
Castrejon, J. Luis,Lavergne, Sidonie N.,El-Sheikh, Ayman,Farrell, John,Maggs, James L.,Sabbani, Sunil,O'Neill, Paul M.,Kevin Park,Naisbitt, Dean J.
p. 184 - 192
(2011/02/16)

Synthesis and reactions of nitroso sulphamethoxazole with biological nucleophiles: Implications for immune mediated toxicity
Sulphamethoxazole hydroxylamine (SMX-NHOH) and nitroso sulphamethoxazole (SMX-NO) were prepared by a modified literature procedure. SMX-NO produced a complex set of unstable intermediates with sulphur nucleophiles, but did not react with amino containing compounds. No reactions were observed between sulphamethoxazole (SMX) / SMX-NHOH and the nucleophiles used in this study. Thus antigens formed from N-oxidation of SMX are likely to be unstable in vivo.
Naisbitt, Dean J.,Neill, Paul M.,Pirmohamed, Munir,Park, B. Kevin
p. 1511 - 1516
(2007/10/03)

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Chemical Properties

Melting Point: >180°C (dec.)
Boiling Point: 472.9°Cat760mmHg
Flash Point:239.8°C
Density: 1.53g/cm³
Solubility:DMSO (Slightly), Ethyl Acetate (Slightly, Heated), Methanol (Slightly, Heated)
Storage Temp.:-20?C Freezer, Under Inert Atmosphere
Vapor Pressure: 4.1E-09mmHg at 25°C
PKA: 5.90±0.50(Predicted)
BRN: 6338308
PSA: 110.01000
LogP: 3.33550

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