Substituent-controlled reactivity in the Nazarov cyclisation of allenyl vinyl ketones
Alkyl substitution α to the ketone of an allenyl vinyl ketone enhances Nazarov reactivity by inhibiting alternative pathways involving the allene moiety and through electron donation and/or steric hindrance. This substitution pattern also accelerates Naza
Marx, Vanessa M.,Stoddard, Rhonda L.,Heverly-Coulson, Gavin S.,Burnell, D. Jean
p. 8098 - 8104
(2011/09/14)
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