The 2,4,6-tris(trifluoromethyl)phenyl group: Methyl and vinyl ketones and related chemistry
2,4,6-Tris(trifluoromethyl)phenyllithium (1) reacts with acetaldehyde and acrolein to give the corresponding alcohols 5 and 8. Oxidation of the alcohols with the CrO3-pyridine complex affords the acetophenone 3 and the vinyl ketone 7 respectively. The reactions of 1 with trifluoroacetic anhydride and trimethylsilyl trifluoroacetate give low to moderate yields of the trifluoroacetophenone 6.
New Aspects of the Chemistry of 2,4,6-Tris(trifluoromethyl) Benzoic Acid and Related Compounds
1,3,5-Tris(trifluoromethyl)benzene reacts with n-butyllithium and carbon dioxide to give a high yield of 2,4,6-tris(trifluoromethyl)benzoic acid.The acid has been well characterized by spectral and pKa data.The acid chloride is formed only slow
Filler, Robert,Gnandt, William K.,Chen, Wei,Lin, Shan
p. 99 - 105
(2007/10/02)
More Articles about upstream products of 135103-73-0