Simple synthesis of optically active 2-fluoropropanoic acid and analogs of high enantiomeric purity
A very simple synthesis of optically active 2-fluoropropanoic acid 1 (R=CH3, R′=H) and analogs of high enantiomeric purity was developed using the sulfonates 2 of the corresponding optically active 2-hydroxycarboxylic esters and potassium fluor
Fritz-Langhals, Elke,Schuetz, Gabi
p. 293 - 296
(2007/10/02)
The hydrogenation of fluoroolefins
Palladium catalysts are found to selectively hydrogenate fluoroolefins without hydrogenolytic cleavage of the carbon-fluorine bond. Since a large number of methods are available for the preparation of unsaturated organofluoro compounds this constitutes a general synthetic route to sp3-fluorinated molecules.
Allmendinger,Dandois,Walliser
p. 2735 - 2736
(2007/10/02)
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