σ-Alane complexes of chromium, tungsten, and manganese
Photolytic ligand displacement and salt metathesis routes have been exploited to give access to κ1 σ-alane complexes featuring Al-H bonds bound to [W(CO)5] and [Cp′Mn(CO) 2] fragments, together with a related κ2 complex of [Cr(CO)4]. Spectroscopic, crystallographic, and quantum chemical studies are consistent with the alane ligands acting predominantly as σ-donors, with the resulting binding energies calculated to be marginally greater than those found for related dihydrogen complexes.
Riddlestone, Ian M.,Edmonds, Sian,Kaufman, Paul A.,Urbano, Juan,Bates, Joshua I.,Kelly, Michael J.,Thompson, Amber L.,Taylor, Russell,Aldridge, Simon
p. 2551 - 2554
(2012/03/22)
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