O-Sulfinylation of alcohols with methanesulfonyl cyanide or p-toluenesulfonyl cyanide
Reaction of p-toluenesulfonyl cyanide or methanesulfonyl cyanide with alcohols in the presence of 1,8-diazabicyclo[5.4.0]under-7-ene (DBU) or 1,4-diazabicyclo[2.2.2]octane (DABCO) gives sulfinates in good yield. A mechanistic scheme involving sulfinyl cyanates 9 and 21 is suggested.
Barton, Derek H. R.,Jaszberenyi, Joseph Cs.,Theodorakis, Emmanouil A.
O-sulfinylation with methanesulfonyl cyanide or p-toluenesulfonyl cyanide and DBU
Reaction of methanesulfonyl cyanide or p-toluenesulfonyl cyanide with alcohols in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) gives sulfinates in good yield. A mechanistic scheme involving sulfinyl cyanates is suggested.
Barton,Jaszberenyi,Theodorakis
p. 2585 - 2588
(2007/10/02)
More Articles about upstream products of 135802-73-2