Tetrahedron p. 9167 - 9178 (1991)
Update date:2022-07-30
Topics:
Barton, Derek H. R.
Jaszberenyi, Joseph Cs.
Theodorakis, Emmanouil A.
Reaction of p-toluenesulfonyl cyanide or methanesulfonyl cyanide with alcohols in the presence of 1,8-diazabicyclo[5.4.0]under-7-ene (DBU) or 1,4-diazabicyclo[2.2.2]octane (DABCO) gives sulfinates in good yield. A mechanistic scheme involving sulfinyl cyanates 9 and 21 is suggested.
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Doi:10.3987/COM-12-S(N)1
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