136000-12-9

Basic information

• Product Name: Benzeneacetaldehyde, a-[1-(ethylthio)-2,2,2-trifluoroethylidene]-, (E)-
• CAS NO: 136000-12-9
• Molecular Formula: C12H11F3OS
• Molecular Weight: 260.28
• Mol File: 136000-12-9.mol

Chemical Properties

• CAS DataBase Reference: Benzeneacetaldehyde, a-[1-(ethylthio)-2,2,2-trifluoroethylidene]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetaldehyde, a-[1-(ethylthio)-2,2,2-trifluoroethylidene]-, (E)-(136000-12-9)
• EPA Substance Registry System: Benzeneacetaldehyde, a-[1-(ethylthio)-2,2,2-trifluoroethylidene]-, (E)-(136000-12-9)

Safety Data

• Hazardous Substances Data: 136000-12-9(Hazardous Substances Data)

Upstream product

• 20733-13-5 ethanethiolate 
• 119197-24-9 3-chloro-4,4,4-trifluoro-2-phenyl-but-2-enal 
• 75-08-1 ethanethiol 

Relevant articles and documents

Reactivity of β-(trifluoromethyl) acroleins towards primary alkyl (or aryl) amines: synthesis of trifluoromethyl)-1-aza-1,3-dienes and secondary (trifluoromethyl) allylamines

Vilsmeier's reaction on trifluoroketones leads to β-chloro-β(trifluoromethyl)acroleins.The addition of primary alkyl- or aryl-amines to these acroleins leads in all cases to the formation of stable (trifluoromethyl)-1-aza-1,3-dienes which can be transform

Synthesis of trifluoromethylalkenes and alkynes. Trifluoromethyl captodative olefins

β-ethylthio-β-trifluoromethylketones 3 and aldehydes 4 are easily prepared from β-chloroolefines 5 and 6. Trifluoromethylalkynes 7 and captodative alkenes 8 are obtained by reaction of KOH on aldehydes 6 or 4.