Enhanced catalytic decomposition of a phosphate triester by modularly accessible bimetallic porphyrin dyads and dimers
A series of metalloporphyrin dimers were modularly prepared and shown to catalyze the methanolysis of a phosphate triester, yielding rates that are large compared to the rate of the uncatalyzed reaction. Up to 1300-fold rate acceleration can be achieved v
Totten, Ryan K.,Ryan, Patrick,Kang, Byungman,Lee, Suk Joong,Broadbelt, Linda J.,Snurr, Randall Q.,Hupp, Joseph T.,Nguyen, Sonbinh T.
p. 4178 - 4180
(2012/05/05)
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