Synthesis of guaia-4(5)-en-11-ol, guaia-5(6)-en-11-ol, aciphyllene, 1- epi -melicodenones C and E, and other guaiane-type sesquiterpenoids via the diastereoselective epoxidation of guaiol
The diastereomeric ratio of epoxidation of the internally bridged carbon-carbon double bond of guaiol (1a) is strongly influenced by the combined effects of the types of remote protecting groups on the hydroxyisopropyl side chain, choice of solvent, and e
Huang, An-Cheng,Sumby, Christopher J.,Tiekink, Edward R.T.,Taylor, Dennis K.