Synthesis of guaia-4(5)-en-11-ol, guaia-5(6)-en-11-ol, aciphyllene, 1- epi -melicodenones C and E, and other guaiane-type sesquiterpenoids via the diastereoselective epoxidation of guaiol

DOI: 10.1021/np500611z

Source and publish data:

Journal of Natural Products p. 2522 - 2536 (2014)

Update date:2022-08-04

Topics: Synthesis

Authors:

Huang, An-Cheng

Sumby, Christopher J.

Tiekink, Edward R.T.

Taylor, Dennis K.

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Article abstract of DOI:10.1021/np500611z

The diastereomeric ratio of epoxidation of the internally bridged carbon-carbon double bond of guaiol (1a) is strongly influenced by the combined effects of the types of remote protecting groups on the hydroxyisopropyl side chain, choice of solvent, and e

Full text of DOI:10.1021/np500611z

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