- New solid solutions based on Bi10M3X18 and Bi6X7 (M = Zr, Hf; X = Cl, Br)
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The Bi10Hf3Cl18-xBr, and Bi 10Zr3Cl18-xBrx(x = 4.5, 9, 13.5) and Bi6Cl7-xBrx (x = 1.75, 3.5, 5.25) solid solutions containing Bi95+ homopolycations and mixed chloride-bromide anions have been obtained by the ampoule method. The unit cell parameters of these samples have been determined. The unit cell parameters are a linear function of the percentage (at. %) of the substituted chlorine, which indicates that these systems form a continuous series of solid solutions. Analogous solid solutions Bi10Hf3Br18-xI x and Bi10Zr3Br18-xIx (x = 4.5, 9, 13.5) are not formed.
- Savilov,Kuznetsov,Donets,Popovkin
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p. 335 - 338
(2008/10/08)
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