Palladium-catalyzed hiyama couplings of α-silylenoates and α-silylenamides
The Hiyama couplings of both α-silylenoates and α-silylenamides are described. These sensitive substrate classes require particularly specific conditions, employing both appropriate silicon-based species and a silver additive to realize high yields of the coupling products. Regioselective platinum-catalyzed hydrosilylations provide a direct and convenient entry into these stereodefined trisubstituted alkenes.
Rooke, Douglas A.,Ferreira, Eric M.
supporting information; experimental part
p. 3328 - 3331
(2012/08/08)
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