1383440-57-0Relevant articles and documents
Palladium-catalyzed hiyama couplings of α-silylenoates and α-silylenamides
Rooke, Douglas A.,Ferreira, Eric M.
supporting information; experimental part, p. 3328 - 3331 (2012/08/08)
The Hiyama couplings of both α-silylenoates and α-silylenamides are described. These sensitive substrate classes require particularly specific conditions, employing both appropriate silicon-based species and a silver additive to realize high yields of the coupling products. Regioselective platinum-catalyzed hydrosilylations provide a direct and convenient entry into these stereodefined trisubstituted alkenes.
