138619-95-1Relevant articles and documents
Metal-Catalyzed Organic Photoreactions. Chemo- and Regioselectivities in the CuCl2-Induced Photooxidation of Olefins.
Sato, Tadashi,Yonemochi, Shin-ichi
, p. 7375 - 7384 (1994)
Copper(II) chloride induced the chemo and regioselective chlorohydroperoxidation, as well as the site-selective chlorination of olefins, under photooxygenation conditions.
A SIMPLE SYNTHESIS OF 4-CYCLOHEPTENE-1-CARBOXYLIC ACID
Zakharkin, L. I.,Guseva, P. V.
, p. 1055 - 1056 (2007/10/02)
A simple method is proposed for the production of 4-cycloheptene-1-carboxylic acid from 1,5-cyclooctadiene through 2-chloro-5-cycloocten-1-one oxime.
OXYCHLORINATION OF ALKENES BY CHLOROCHROMATE REAGENTS: A FACILE PREPARATION OF α-CHLOROKETONES, AND COMPETITION BY SUBSTITUENT-DIRECTED OXIDATION.
Guerrero, Angel F.,Kim, Ho-jin,Schlecht, Matthew F.
, p. 6707 - 6710 (2007/10/02)
Cyanopyridinium chlorochromate effects a facile preparation of α-chloroketones from simple alkenes, cycloocta-1,5-diene and cyclododeca-1,5,9-triene; 1-methylcaclooct-4-en-1-ol undergoes oxidative cyclization.
Metal-Catalyzed Organic Photoreactions. One-Step Synthesis of Chlorinated Ketones from Olefins by Photooxidation in the Presence of Iron(III) Chloride
Kohda, Akira,Ueda, Keiko,,Sato, Tadashi
, p. 509 - 515 (2007/10/02)
Under photooxidation in pyridine in the presence of FeCl3, mono- and disubstituted olefins gave α-chloro ketones, while tri- and tetrasubstituted olefins gave dichloro ketones with a C-C bond cleavage.The reaction was interpreted in terms of an electron-transfer mechanism occurring within the coordination sphere of the iron ion