138906-08-8

Basic information

• Product Name: S-phenyl pyrrolidine-1-carbothioate
• CAS NO: 138906-08-8
• Molecular Formula: C₁₁H₁₃NOS
• Molecular Weight: 207.292
• Mol File: 138906-08-8.mol

Chemical Properties

• Boiling Point: 327.1°C at 760 mmHg
• Flash Point: 151.6°C
• Density: 1.21g/cm³
• Vapor Pressure: 0.000206mmHg at 25°C
• Refractive Index: 1.616
• CAS DataBase Reference: S-phenyl pyrrolidine-1-carbothioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-phenyl pyrrolidine-1-carbothioate(138906-08-8)
• EPA Substance Registry System: S-phenyl pyrrolidine-1-carbothioate(138906-08-8)

Safety Data

• Hazardous Substances Data: 138906-08-8(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 123-75-1 pyrrolidine 
• 201230-82-2 carbon monoxide 
• 882-33-7 diphenyldisulfane 

Relevant articles and documents

Achieving functional group diversity in parallel synthesis: solution-phase synthesis of a library of ureas, carbamates, thiocarbamates, and amides using carbamoylimidazolium salts

A convenient protocol for the parallel solution-phase synthesis of a library of thiocarbamates, ureas, carbamates, and amides from carbamoylimidazolium salts has been developed. The crystalline carbamoylimidazolium salts are readily synthesized from secon

A facile method for the synthesis of thiocarbamates: Palladium-catalyzed reaction of disulfide, amine, and carbon monoxide

(Equation Presented) A new method for the synthesis of thiocarbamates has been developed. When dialkyl or diaryl disulfides were allowed to react with secondary amines and carbon monoxide in the presence of a catalytic amount of a palladium complex, the thiocarbamates were obtained in moderate to good yields. In contrast to that of secondary amines, in the reaction of a primary amine, no formation of thiocarbamate was confirmed, but urea was formed in good yield.

REACTIONS OF UNSTABLE DIALKYLCARBAMOYL LITHIUMS WITH SULFUR COMPOUNDS

Unstable dialkylcarbamoyl lithiums, generated from the reaction of lithium dialkylamides with carbon monoxide, were successfully trapped by sulfur compounds (elemental sulfur, disulfides, carbon disulfide, and carbonyl sulfide) at low temperature, through their potent affinity with a sulfur atom.These efficient reactions were also applied to development of a facile synthetic method for thiocarbamates, useful herbicides, and thiooxamates.