140171-39-7Relevant articles and documents
CHEMISTRY AND SYNTHETIC POTENTIAL OF THE REACTIONS OF 3-CHLORO-1,3-ALKADIEN-5-ONES WITH SODIUM METHOXIDE
Melikyan, G. G.,Tosunyan, A. A.,Babayan, E. V.,Atanesyan, K. A.,Badanyan, Sh. O.
, p. 1802 - 1807 (2007/10/02)
The reactions of (E)- and (Z)-3-chloro-1,3-alkadien-5-ones with sodium methoxide were investigated.The reactions from a process of successive interaction of the substrates with three molecules of the reagent with alternation of the recipient atom (C3-C1-C3).The introduction of a methyl group at position 2 of the substrate molecule gives rise to regioselective reaction at the C3-C4 double bond.
