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High purity Various Specifications Sodium methoxide
Cas No: 124-41-4
USD $ 100.0-100.0 / Kilogram 1 Kilogram 10000 Kilogram/Day Metric Ton/Day Zibo Hangyu Import&Export Co., Ltd Contact Supplier
124-41-4 CH3NaO Sodium methanolate
Cas No: 124-41-4
No Data 1 Metric Ton Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
Sodium methanolate,Sodium methanolate 124-41-4 price,supply Sodium methanolate 124-41-4, Sodium Methanolate 25%
Cas No: 124-41-4
No Data 1000 Kilogram 1000 Metric Ton/Day Shandong Xinhua Pharmaceutical Co.,Ltd Contact Supplier
High purity Various Specifications Sodium methoxide CAS:124-41-4
Cas No: 124-41-4
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Sodium methanolate
Cas No: 124-41-4
USD $ 1.0-1.0 / Kilogram 1 Kilogram 1000 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier
High Quality 99% Sodium methanolate 124-41-4 ISO Producer
Cas No: 124-41-4
USD $ 0.1-0.1 / Gram 1 Gram 100 Metric Ton/Year Xi'an Xszo Chem Co., Ltd. Contact Supplier
Sodium methoxide
Cas No: 124-41-4
USD $ 2.0-3.0 / Kilogram 1 Kilogram 50 Metric Ton/Day EAST CHEMSOURCES LIMITED Contact Supplier
Amadis Chemical offer CAS#124-41-4;CAT#A805230
Cas No: 124-41-4
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Sodium Methoxide
Cas No: 124-41-4
No Data 1 Metric Ton 1 million Metric Ton/Year COLORCOM LTD. Contact Supplier
Sodium methoxide
Cas No: 124-41-4
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 3000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier

124-41-4 Usage

Outline

Sodium methanolate is one of alkoxides that are generated by methanol. Its chemical formula is CH3ONa. It is strong base that is commonly used in organic synthesis. Sodium methanolate is often stored in methanol, ethanol or the like alcohol solvent. It can generate suspension when it dissolves in ether. It can decompose into methanol and sodium hydroxide with water: CH3ONa + H2O→CH3OH + NaOH Sodium methanolate product has two forms: solid and liquid. Solid is pure sodium methanolate. The liquid is methanol solution of sodium methanolate and the content of sodium methylate is 27.5% to 31%. Liquid sodium methanolate is colorless or slightly yellow viscous liquid. It is sensitive to oxygen. It is flammable, explosive and easily hygroscopic. It is soluble in methanol and ethanol, and can decompose into methanol and sodium hydroxide with water. It decomposes at 126.6℃ in the air. It is not soluble in benzene and toluene. It is strong irritant and highly corrosive. Sodium methanolate can be used as condensing agent, strong alkaline catalyst and methoxy agent for the preparation of vitamin B1, vitamin A, sulfadiazine and other drugs. Few can be used in production of pesticides. It can also be used as catalyst in processing edible fats and oils (especially processing lard). It is used as analytical reagent. Solid sodium methanolate is colorless amorphous powder. It is sensitive to oxygen, and it is flammable. It is soluble in methanol and ethanol, and can decompose into methanol and sodium hydroxide with water. It decomposes at 126.6℃ in the air. It is mainly used for the production of sulfa drugs, VB6 and VA. Sodium methylate is a kind of catalyst for organic synthesis. It can be used for the production of pesticides and oil processing industries. Solid sodium methanolate and sodium methoxide methanol solution Sodium methylate is a kind of mature chemical products. It has several decades of production history in China. The overall price is high in the south than in the north. Its price is 4500 yuan/T in the southwest, and 4,000 yuan/T in Shandong. Its price changed little with the increase of methanol’s price in 2004. The profit of per ton of product is 500 to 700.

Soda process for producing sodium methylate

Sodium methylate is prepared by the reaction of methanol with sodium hydroxide for soda method. Their reaction is as follows: CH3OH + NaOH→CH3ONa + H2O 1. The preparation of methanol lye Crush the solid sodium hydroxide. Then add it into melting pot base containing methanol (99.8%) in proportion. Start circulating pump, and dissolve the sodium hydroxide below 70℃. When its content is 20% to 23%, cool down to 40℃ and inject into the settling tank. Stand 12h and spare. 2. The preparation of sodium methylate Pass into the steam to the vaporization pot and reaction tower mezzanine. Heat it and control the temperature at 85~100℃. Add anhydrous methanol to vaporization pot at the flow rate of 180L/h. Meanwhile add methanol lye in the top of the reaction tower at the flow rate of 25kg/h. Methanol gas containing 2% of water produced by the reaction from the reaction distill the reaction tower overhead into the purification distillation column to remove water. Then it becomes absolute methanol recycling. Control the temperature of reaction bottoms (i.e. vaporization pot) at 65~70℃, and check the bottoms. When containing 27%~31% Sodium methanolate, 1% or less of the free base, products are obtained. The yield is 86% (as sodium hydroxide). Fixed consumption of the process is as follows: methanol (95%) 973kg/t, sodium hydroxide (99.5%) 209kg/t.

Sodium process for producing sodium methylate

Sodium metal and methanol as raw materials, using intermittent production process to produce methanol solution of sodium methylate. The reaction is as follows: 2CH3OH + 2Na→2CH3ONa + H2↑ The production process is mainly divided into four parts: 1. Feeding step. Industrial methanol is pumped into methanol metering tank. 120kg of sodium metal is added into the reaction kettle. 2. Nitrogen substitution step. Close feed valve and vent valve. Purged with nitrogen into the reactor so that the index reached 0.1MPa. Open vent valve to remove the pressure, and repeat three times under reflux. The vent valve remains open to continue introducing nitrogen. 3. Reaction step. The cooling water is fed to the condenser. Methanol is immediately added to the methanol tank (note methanol addition rate). Nitrogen is stopped after 5~10min. Methanol is continuously added. 820kg of methanol is added in 2~3h and then the feed valve is closed. The reaction is continued for 2~3h until the reaction mixture has no bubbles. 4. Reconciliation step. The product is added into the harmonic tank. Sample and analysis. Reconcile to the desired concentration and barrels.

The comparison soda process with sodium process

The content of methanol alkaline get by sodium method is higher, more reliable and stable than alkaline method. And the content of free alkali is low. Sodium methylate prepared by sodium method can take off a lot of alcohol and other impurities from sodium in the reaction. The content of Na2CO3 in sodium method is lower than in alkaline method, which can improve product quality and yield of the users.

Solution quality reference standard

Item Index Appearance colorless to pale yellow viscous liquid Content (total base number) 29.5%~31.0% Sodium methoxide (NaOCH3) 28.9%~31.0% Sodium hydroxide (NaOH) ≤0.5% Sodium carbonate (Na2CO3) ≤0.1% Water (H2O) ≤0.2% Methanol 69.0%~70.7%

How to separate solid sodium hydroxide and sodium methylate

1. Dissolved in water (sodium alcoholate reacts violently with water to generate alcohol and sodium hydroxide) 2. Distillation (separate alcohol) 3. Evaporation (separate sodium hydroxide) 4. Try to dry alcohol to anhydrous state (repeated distillation) 5. Add sodium to generate sodium alcohol 6. Distill alcohol to get solid alcohol sodium. (It should be avoided being exposed to the air when distilling. If it is exposed to the air or it is taken down before drying up and cooling, the state of alcohol sodium that is separated out is not well. The good one is white. if not, it will be tan is. But it doesn’t have any great impact. It is easy to be prepared.)

Production Process

Solid sodium hydroxide and methanol mix at a certain proportion. After stirring the mixture to dissolve, solid impurities are removed by sedimentation and clarification. The clear liquid is pumped into the top of the dehydration reaction column, while the refined methanol vapor is added from the bottom of the tower with continuous dehydration reaction. Then the product can be obtained from tower bottom. Aqueous methanol vapor is purified from the top of the column into the distillation system, while anhydrous methanol can be used repeatedly.

Identification test

It can react with oxygen and carbon dioxide. It decomposes in water. Sodium test of the solution (IT-28) is positive. Take 0.1m1 5% sulfuric acid and 0.2ml potassium permanganate solution (TS-193), and add 1 drop of 1% aqueous solution of the sample. After placing 5min, add 0.2ml 25% sodium sulfite solution and 3ml sulfate. Then add 0.2ml chromium changed acid solution (TS-l66). The solution is amaranth to purple.

Chemical properties

Colorless amorphous fine powder. Dissolved in methanol, ethanol.

Uses

1. Sodium methoxide can be used as alkaline condensing agent and catalyst in organic synthesis. It can be used to synthesize perfumes, dyes and the like. It is also the raw material of vitamin B1, A and sulfadiazine. 2. It can be used as condensing agent in organic synthesis and catalyst in edible oil process. It is also the important raw material to synthesize sulfadiazine, sulfamethoxazole, sulfa synergist and the like. 3. It is the main raw material used for medicine, pesticide. It is also used in dyes and chemical fiber industry.4. Fatty transesterification catalyst. It can change the fat structure so that it is suitable for margarine. It must be removed in the final food.5. It is mainly used as condensing agent, strong alkaline catalyst and methoxy agent. It can be used for the preparation of vitamin B1 and A, sulfadiazine and other drugs. And little can be used in the production of pesticides. It can also be used as the catalyst for processing edible fats and oils (especially processing lard). It can also be used as analytical reagent.6. It is widely used in perfumes, dyes and other industries. It is mainly used as condensing agent, strong alkaline catalyst and methoxy agent for the preparation of vitamin B1 and A, sulfadiazine and other drugs. Little can be used in the production of pesticides. It can also be used as the catalyst for processing edible fats and oils (especially processing lard). It can also be used as analytical reagent.7. It can be used as condensing agent in organic synthesis.

Production method

1. Xylene (water content < 0.05) and metallic sodium are added into reaction vessel. Heat the reaction vessel to 130~140℃, keep for 1h and stop heating. After rapid stirring for 1h, use cooling water to 50℃. Then start to dropwise add anhydrous methanol (water content < 0.1%), and appropriately add dry xylene. The dropping rate depends on the flow rate of methanol and the release of hydrogen. After the dropwise addition finishes, heat it under reflux for 4h and cool to room temperature to obtain sodium methanolate slurry. Xylene can be recovered by vacuum distillation and then dried in vacuo for 4h. Sodium methanolate can be obtained by nitrogen cooling. The yield is over 90%. Sodium methanolate can also be prepared by the continuous reaction and dehydration of sodium hydroxide with methanol at 85~100℃. 2. It can be obtained by the reaction of sodium hydroxide and methanol in benzene.

Category

Corrosive materials

Chemical Properties

white powder

Uses

Sodium methoxide is mainly used as a condensation agent, a strong alkaline catalyst and a methoxylating agent for the production of vitamin B1 and A, sulfadiazine and other drugs, and in small quantities for the production of pesticides. It is also used as a catalyst for treatment ofedible fats and oils, as an intermediate inmany synthetic reactions, to prepare sodiumcellulosate; and as a reagent in chemicalanalysis.

General Description

Sodium methylate is a white amorphous powder. It reacts with water to form sodium hydroxide, a corrosive material, and methyl alcohol, a flammable liquid. The heat from this reaction may be sufficient to ignite surrounding combustible material or the sodium methylate itself if the water is present in only small amounts. It is used to process edible fats and oils, and to make other chemicals.

Air & Water Reactions

Highly flammable. Ignites in moist air [Wischmeyer 1966]. Reacts with water to produce a mixed solution of sodium hydroxide and methyl alcohol.

Reactivity Profile

SODIUM METHYLATE is a strong base. Reacts with light metals forming H2 gas, with fire and explosion hazards. Too rapid addition of sodium methylate to a mixture of chloroform and methanol initiated an uncontrolled exothermic reaction between the chloroform and the methylate that caused a violent explosion [MCA Case History 693 1961]. Sodium methoxide is incompatible with 4-chloronitrobenzene and fluorinated cyclopropenyl methyl ethers, such as perfluoromethoxycyclopropene. The reactions are vigorous and may initiate ignition [Bretherick, 1995, pg. 191].

Hazard

(Solid) Flammable when exposed to heat or flame. (Solution) Flammable, moderate fire risk.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

A corrosive and irritating material. It hydrolyzes into methanol and sodlum hydroxide. May ignite spontaneously in moist air. Flammable when exposed to heat or flame. Ignites on contact with water, Violent reaction with (CHCl3 + CH3OH), (methyl azide + dimethylmalonate), FClO3. When heated to decomposition it emits toxic fumes of Na2O.

Purification Methods

It behaves in the same way as sodium ethoxide. It is hygroscopic and is hydrolysed by moist air to NaOH and MeOH. Material that has been kept under N2 should be used. If erratic results are obtained, even with recently purchased NaOMe, it should be freshly prepared thus: Clean Na (37g) cut in 1-3g pieces is added in small portions to stirred MeOH (800mL) in a 2L three-necked flask equipped with a stirrer and a condenser with a drying tube. After all the Na has dissolved, the MeOH is removed by distillation under vacuum, and the residual NaOMe is dried by heating at 150o under vacuum and kept under dry N2 [Burness Org Synth 39 51 1959]. [Beilstein 1 IV 1227.]
InChI:InChI=1/CH3NaO/c1-2;/h2H,1H3;/q;+1

124-41-4 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (46585)  Sodium methoxide, ca 25% w/w in methanol    124-41-4 500ml 405.0CNY Detail
Alfa Aesar (46585)  Sodium methoxide, ca 25% w/w in methanol    124-41-4 2500ml 1046.0CNY Detail
Alfa Aesar (L05673)  Sodium methoxide, 98%    124-41-4 100g 212.0CNY Detail
Alfa Aesar (L05673)  Sodium methoxide, 98%    124-41-4 500g 342.0CNY Detail
Alfa Aesar (L05673)  Sodium methoxide, 98%    124-41-4 2000g 894.0CNY Detail
Alfa Aesar (B21872)  Sodium methoxide, ca 30% w/w in methanol    124-41-4 500ml 190.0CNY Detail
Alfa Aesar (B21872)  Sodium methoxide, ca 30% w/w in methanol    124-41-4 2500ml 547.0CNY Detail
Supelco (33352)  Methanolic Base  0.5 M CH3ONa (0.5N), for GC derivatization 124-41-4 000000000000033352 413.01CNY Detail
Supelco (33080)  Methanolic Base  0.5 M CH3ONa (0.5N), for GC derivatization 124-41-4 000000000000033080 752.31CNY Detail
Sigma-Aldrich (403067)  Sodiummethoxidesolution  ACS reagent, 0.5 M CH3ONa in methanol (0.5N) 124-41-4 403067-100ML 849.42CNY Detail
Sigma-Aldrich (403067)  Sodiummethoxidesolution  ACS reagent, 0.5 M CH3ONa in methanol (0.5N) 124-41-4 403067-250ML 1,264.77CNY Detail
Sigma-Aldrich (403067)  Sodiummethoxidesolution  ACS reagent, 0.5 M CH3ONa in methanol (0.5N) 124-41-4 403067-4X100ML 2,548.61CNY Detail

124-41-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Sodium methoxide

1.2 Other means of identification

Product number -
Other names methanol sodium salt

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:124-41-4 SDS

124-41-4Synthetic route

methanol
67-56-1

methanol

3-Vinylbicyclobutane-1-carbonitrile
51934-08-8

3-Vinylbicyclobutane-1-carbonitrile

A

sodium methylate
124-41-4

sodium methylate

B

3-(2-Methoxyethylidene)cyclobutane-1-carbonitrile
91597-63-6

3-(2-Methoxyethylidene)cyclobutane-1-carbonitrile

C

Z-3-vinyl-3-methoxycyclobutane-1-carbonitrile
91597-62-5

Z-3-vinyl-3-methoxycyclobutane-1-carbonitrile

Conditions
ConditionsYield
With perchloric acid at 20℃; for 5h; Yields of byproduct given;A n/a
B 35%
C n/a
Methyl formate
107-31-3

Methyl formate

2-(carboxymethyl)-4-methoxybenzoic acid
68294-03-1

2-(carboxymethyl)-4-methoxybenzoic acid

A

6-methoxy-1-oxo-1H-isochromene-4-carboxylic acid methyl ester

6-methoxy-1-oxo-1H-isochromene-4-carboxylic acid methyl ester

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
With diethyl ether Erwaermen des danach isolierten Reaktionsprodukts mit konz. wss.Salzsaeure;
methanol
67-56-1

methanol

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
With [Ru4(μ-H)4(CO)12] at 25℃; Rate constant; Equilibrium constant; various carbonyl hydride complexes of Fe, Ru, and Os;
With sodium hydroxide; water at 20℃; Equilibrium constant;
With sodium hydroxide
sodium tetramethoxyborate
18024-69-6

sodium tetramethoxyborate

A

Trimethyl borate
121-43-7

Trimethyl borate

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
at 210 - 240℃; im Vakuum;
210-280°C;
210-280°C;
210-280°C;
methanol
67-56-1

methanol

bis-methoxycarbonyl-methanide
33673-07-3

bis-methoxycarbonyl-methanide

A

sodium methylate
124-41-4

sodium methylate

B

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

Conditions
ConditionsYield
at 25℃; Equilibrium constant;
methanol
67-56-1

methanol

ethyl cyanoacetate anion
31124-95-5

ethyl cyanoacetate anion

A

sodium methylate
124-41-4

sodium methylate

B

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

Conditions
ConditionsYield
at 25℃; Equilibrium constant;
methanol
67-56-1

methanol

4-nitrobenzyl cyanide anion
48129-94-8

4-nitrobenzyl cyanide anion

A

sodium methylate
124-41-4

sodium methylate

B

4-Nitrophenylacetonitrile
555-21-5

4-Nitrophenylacetonitrile

Conditions
ConditionsYield
at 25℃; Equilibrium constant;
methanol
67-56-1

methanol

p-cyano-phenyl-acetonitrile anion
64764-41-6

p-cyano-phenyl-acetonitrile anion

A

4-(cyanomethyl)benzonitrile
876-31-3

4-(cyanomethyl)benzonitrile

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
at 25℃; Equilibrium constant;
methanol
67-56-1

methanol

2-cyanobenzyl cyanide anion
163977-20-6

2-cyanobenzyl cyanide anion

A

(2-cyanophenyl)acetonitrile
3759-28-2

(2-cyanophenyl)acetonitrile

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
at 25℃; Equilibrium constant;
C15H9N6O13(1-)

C15H9N6O13(1-)

A

2,2',4.4',6,6'-hexanitrostilbene
19138-90-0

2,2',4.4',6,6'-hexanitrostilbene

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
In methanol; dimethyl sulfoxide at 25℃; Equilibrium constant;
C15H9N6O13(1-)

C15H9N6O13(1-)

A

2,2',4.4',6,6'-hexanitrostilbene
19138-90-0

2,2',4.4',6,6'-hexanitrostilbene

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
In methanol; dimethyl sulfoxide at 25℃; for 0.0166667h; Rate constant; Equilibrium constant;
2,6-Di-tert-butyl-2-methoxy-2H-thiopyran
104086-30-8

2,6-Di-tert-butyl-2-methoxy-2H-thiopyran

A

sodium methylate
124-41-4

sodium methylate

B

2,6-Bis(1,1-dimethylethyl)thiopyrylium-perchlorat

2,6-Bis(1,1-dimethylethyl)thiopyrylium-perchlorat

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
2,6-Di-tert-butyl-4-methoxy-4H-thiopyran
104086-38-6

2,6-Di-tert-butyl-4-methoxy-4H-thiopyran

A

sodium methylate
124-41-4

sodium methylate

B

2,6-Bis(1,1-dimethylethyl)thiopyrylium-perchlorat

2,6-Bis(1,1-dimethylethyl)thiopyrylium-perchlorat

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
2,6-Di-tert-butyl-4-methoxy-4-methyl-4H-thiopyran
104086-39-7

2,6-Di-tert-butyl-4-methoxy-4-methyl-4H-thiopyran

A

sodium methylate
124-41-4

sodium methylate

B

2,6-di-t-butyl-4-(methyl)thiopyrylium tetrafluoroborate

2,6-di-t-butyl-4-(methyl)thiopyrylium tetrafluoroborate

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
2,4,6-Tri-tert-butyl-4-methoxy-4H-thiopyran
104086-40-0

2,4,6-Tri-tert-butyl-4-methoxy-4H-thiopyran

A

sodium methylate
124-41-4

sodium methylate

B

2,4,6-tri-tert-butyl thiopyrylium perchlorate

2,4,6-tri-tert-butyl thiopyrylium perchlorate

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
2,4,6-Tri-tert-butyl-2-methoxy-2H-thiopyran
104086-32-0

2,4,6-Tri-tert-butyl-2-methoxy-2H-thiopyran

A

sodium methylate
124-41-4

sodium methylate

B

2,4,6-tri-tert-butyl thiopyrylium perchlorate

2,4,6-tri-tert-butyl thiopyrylium perchlorate

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
4-Methoxy-4-methyl-2,6-diphenyl-4H-pyran
104086-45-5

4-Methoxy-4-methyl-2,6-diphenyl-4H-pyran

A

4-methyl-2,6-diphenylpyrylium perchlorate

4-methyl-2,6-diphenylpyrylium perchlorate

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
2-Methoxy-4-methyl-2,6-diphenyl-2H-pyran
104086-28-4

2-Methoxy-4-methyl-2,6-diphenyl-2H-pyran

A

4-methyl-2,6-diphenylpyrylium perchlorate

4-methyl-2,6-diphenylpyrylium perchlorate

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
4-tert-Butyl-2-methoxy-2,6-diphenyl-2H-pyran
104086-29-5

4-tert-Butyl-2-methoxy-2,6-diphenyl-2H-pyran

A

sodium methylate
124-41-4

sodium methylate

B

2,6-diphenyl-4-tert-butylpyrilium perchlorate

2,6-diphenyl-4-tert-butylpyrilium perchlorate

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
Sodium 1,1-dimethoxy-2,4,6-trinitrocyclohexadienate-2,5
107047-08-5, 36144-30-6

Sodium 1,1-dimethoxy-2,4,6-trinitrocyclohexadienate-2,5

A

sodium methylate
124-41-4

sodium methylate

B

1-methoxy-2,4,6-trinitrobenzene
606-35-9

1-methoxy-2,4,6-trinitrobenzene

Conditions
ConditionsYield
In methanol at 25℃; various initial concetration also with potasium salt, var. slovents and additive;
C16H13N2O6(1-)*Na(1+)

C16H13N2O6(1-)*Na(1+)

A

sodium methylate
124-41-4

sodium methylate

B

1,3-dinitro-4-phenanthryl methyl ether
99268-62-9

1,3-dinitro-4-phenanthryl methyl ether

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
C9H8N3O6(1-)*Na(1+)

C9H8N3O6(1-)*Na(1+)

A

2,6-dinitro-4-cyanoanisole
19018-96-3

2,6-dinitro-4-cyanoanisole

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant;
C8H8N3O7(1-)*Na(1+)

C8H8N3O7(1-)*Na(1+)

A

2,4,6-Trinitrotoluene
118-96-7

2,4,6-Trinitrotoluene

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
In methanol; dimethyl sulfoxide at 25℃; Rate constant; Equilibrium constant;
Natrium-1-cyan-2-methoxy-3.5-dinitro-2H-cyclohexadienylid

Natrium-1-cyan-2-methoxy-3.5-dinitro-2H-cyclohexadienylid

A

3,5-dinitrobenzonitrile
4110-35-4

3,5-dinitrobenzonitrile

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
In methanol; dimethyl sulfoxide at 25℃; Equilibrium constant;
C8H8ClN2O6(1-)*Na(1+)

C8H8ClN2O6(1-)*Na(1+)

A

5-chloro-4-methoxy-1,3-dinitrobenzene
23789-10-8

5-chloro-4-methoxy-1,3-dinitrobenzene

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
With (decomposition) In methanol at 25℃; Equilibrium constant; Rate constant;
With (decomposition); barium(II) chloride In methanol at 25℃; Equilibrium constant; other catalyst;
C9H8F3N2O6(1-)*Na(1+)

C9H8F3N2O6(1-)*Na(1+)

A

2-methoxy-1,3-dinitro-5-(trifluoromethyl)benzene
317-70-4

2-methoxy-1,3-dinitro-5-(trifluoromethyl)benzene

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
With (decomposition) In methanol at 25℃; Equilibrium constant; Rate constant;
C10H11N2O8(1-)*Na(1+)

C10H11N2O8(1-)*Na(1+)

A

methyl 4-methoxy-3,5-dinitrobenzoate
29544-89-6

methyl 4-methoxy-3,5-dinitrobenzoate

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
In methanol at 25℃; Equilibrium constant; Kinetics;
With (decomposition); barium(II) chloride In methanol at 25℃; Equilibrium constant;
With (decomposition) In methanol at 25℃; Equilibrium constant; Rate constant;
C10H11N2O8(1-)*Na(1+)

C10H11N2O8(1-)*Na(1+)

A

2-methoxy-3,5-dinitro-benzoic acid methyl ester
38102-00-0

2-methoxy-3,5-dinitro-benzoic acid methyl ester

B

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
With (decomposition) In methanol at 25℃; Equilibrium constant; Rate constant;
With (decomposition); barium(II) chloride In methanol at 25℃; Equilibrium constant; Rate constant; other catalyst;
1,2-dibromo-3-methoxypropane
5836-66-8

1,2-dibromo-3-methoxypropane

sodium amide

sodium amide

A

sodium methylate
124-41-4

sodium methylate

B

propargyl alcohol methyl ether
627-41-8

propargyl alcohol methyl ether

C

methylacetylene sodium

methylacetylene sodium

Trimethyl borate
121-43-7

Trimethyl borate

sodium hydride

sodium hydride

nitrogen

nitrogen

A

sodium methylate
124-41-4

sodium methylate

B

sodium borate

sodium borate

Conditions
ConditionsYield
at 230 - 270℃;
6-chloronicotinonitrile
33252-28-7

6-chloronicotinonitrile

sodium methylate
124-41-4

sodium methylate

6-methoxynicotinonitrile
15871-85-9

6-methoxynicotinonitrile

Conditions
ConditionsYield
In methanol for 20h; Heating / reflux;100%
With 1,4-dioxane; methanol
In methanol Reflux;8.8 g
2-chloro-4,6-dimethylnicotinonitrile
14237-71-9

2-chloro-4,6-dimethylnicotinonitrile

sodium methylate
124-41-4

sodium methylate

3-cyano-4,6-dimethyl-2-methoxypyridine
65515-39-1

3-cyano-4,6-dimethyl-2-methoxypyridine

Conditions
ConditionsYield
In methanol for 1h;100%
In methanol at 0℃; for 10h;99%
In methanol at 60℃; for 4h;65%
With methanol
sodium methylate
124-41-4

sodium methylate

4-picolylchloride hydrochloride
1822-51-1

4-picolylchloride hydrochloride

4-(methoxymethyl)pyridine
70199-60-9

4-(methoxymethyl)pyridine

Conditions
ConditionsYield
In methanol at 90℃; for 12h;100%
With methanol
for 4h; Inert atmosphere; Reflux;
sodium methylate
124-41-4

sodium methylate

Benzeneacetamide
103-81-1

Benzeneacetamide

methyl N-benzylcarbamate
5817-70-9

methyl N-benzylcarbamate

Conditions
ConditionsYield
With N-Bromosuccinimide In methanol for 0.166667h; Heating;100%
With methanol; bromine
2,6-dichloropyridine
2402-78-0

2,6-dichloropyridine

sodium methylate
124-41-4

sodium methylate

6-chloro-2-methoxypyridine
17228-64-7

6-chloro-2-methoxypyridine

Conditions
ConditionsYield
In methanol at 60℃; for 24h;100%
In toluene for 24h;
3,4-dichlorotetrahydrothiophene-1,1-dioxide
3001-57-8

3,4-dichlorotetrahydrothiophene-1,1-dioxide

sodium methylate
124-41-4

sodium methylate

trans-3,4-Dimethoxythiolane-1,1-dioxide
27529-59-5, 64944-15-6, 64944-16-7

trans-3,4-Dimethoxythiolane-1,1-dioxide

Conditions
ConditionsYield
In methanol at 58.9 - 63.9℃;100%
N-benzoylpyrrole
5145-65-3

N-benzoylpyrrole

sodium methylate
124-41-4

sodium methylate

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

Conditions
ConditionsYield
In methanol for 14h; Product distribution; Heating;100%
In methanol for 14h; Heating; Yield given;
6-oxabicyclo[3.2.1]oct-3-en-7-one
4720-83-6

6-oxabicyclo[3.2.1]oct-3-en-7-one

sodium methylate
124-41-4

sodium methylate

Conditions
ConditionsYield
In methanol at 25℃; for 12h;100%
Methyl 3,4-anhydro-2,6-dideoxy-α-L-ribo-hexopyranoside
67909-18-6

Methyl 3,4-anhydro-2,6-dideoxy-α-L-ribo-hexopyranoside

sodium methylate
124-41-4

sodium methylate

methyl α-L-oleandropyranoside
4166-79-4

methyl α-L-oleandropyranoside

Conditions
ConditionsYield
In methanol for 18h; Heating;100%
2,4,5,6-Tetrafluoro-1,3-dinitrobenzene
20002-14-6

2,4,5,6-Tetrafluoro-1,3-dinitrobenzene

sodium methylate
124-41-4

sodium methylate

1,2,4-Trifluoro-6-methoxy-3,5-dinitro-benzene

1,2,4-Trifluoro-6-methoxy-3,5-dinitro-benzene

Conditions
ConditionsYield
In methanol Ambient temperature;100%
dichlorure de l'acide N-(phenylmethyl) carbonimidique
6181-92-6

dichlorure de l'acide N-(phenylmethyl) carbonimidique

sodium methylate
124-41-4

sodium methylate

methyl N-benzylchloroformimidate
6392-79-6

methyl N-benzylchloroformimidate

Conditions
ConditionsYield
In diethyl ether for 48h; Heating;100%
In diethyl ether at 25℃;
1,2,3,4-Tetrafluorodibenz<1,4>-oxazepin-11-(10H)-one
123959-09-1

1,2,3,4-Tetrafluorodibenz<1,4>-oxazepin-11-(10H)-one

sodium methylate
124-41-4

sodium methylate

3-methoxy-1,2,4-trifluorobenz<1,4>oxazepin-11(10H)-one
140406-57-1

3-methoxy-1,2,4-trifluorobenz<1,4>oxazepin-11(10H)-one

Conditions
ConditionsYield
In methanol for 1h; Heating;100%
sodium methylate
124-41-4

sodium methylate

5-chloro-6-dichloromethyl-3-phenyl-as-triazine
126542-38-9

5-chloro-6-dichloromethyl-3-phenyl-as-triazine

6-Dimethoxymethyl-5-methoxy-3-phenyl-[1,2,4]triazine
132818-19-0

6-Dimethoxymethyl-5-methoxy-3-phenyl-[1,2,4]triazine

Conditions
ConditionsYield
In methanol Heating;100%
sodium methylate
124-41-4

sodium methylate

<(3R)-5α>-2',2'-Dichlorospiro-3'-one
118348-72-4

<(3R)-5α>-2',2'-Dichlorospiro-3'-one

<(3S)-5α>-2',2'-dimethoxyspiro-3'-one
151475-18-2

<(3S)-5α>-2',2'-dimethoxyspiro-3'-one

Conditions
ConditionsYield
In methanol for 0.0833333h; Mechanism; Ambient temperature;100%
In methanol for 0.0833333h; Ambient temperature;100%
sodium methylate
124-41-4

sodium methylate

4,4'-Bis(brommethyl)-1,1'-binaphthalin
128923-90-0

4,4'-Bis(brommethyl)-1,1'-binaphthalin

4,4'-Bis(methoxymethyl)-1,1'-binaphthalin
128923-91-1

4,4'-Bis(methoxymethyl)-1,1'-binaphthalin

Conditions
ConditionsYield
In methanol for 24h; Heating;100%
sodium methylate
124-41-4

sodium methylate

5-tert-butylamino-3,6-dichloro-1,2,4-triazine
83403-49-0

5-tert-butylamino-3,6-dichloro-1,2,4-triazine

3-methoxy-5-tert-butylamino-6-chloro-1,2,4-triazine
132434-86-7

3-methoxy-5-tert-butylamino-6-chloro-1,2,4-triazine

Conditions
ConditionsYield
In methanol Ambient temperature;100%
sodium methylate
124-41-4

sodium methylate

2-chloro-6-methylsulphenylpyridine
77145-64-3

2-chloro-6-methylsulphenylpyridine

2-methoxy-6-(methylthio)pyridine
87512-15-0

2-methoxy-6-(methylthio)pyridine

Conditions
ConditionsYield
In methanol for 20h; Heating;100%
sodium methylate
124-41-4

sodium methylate

1-fluoro-1-methoxy-1-phenylacetone

1-fluoro-1-methoxy-1-phenylacetone

1,1-dimethoxy-1-phenyl-2-propanone
57711-28-1

1,1-dimethoxy-1-phenyl-2-propanone

Conditions
ConditionsYield
In methanol for 0.5h; Ambient temperature;100%
sodium methylate
124-41-4

sodium methylate

(1-chloro-1-phenyl-2-propylidene)cyclohexylamine
87207-67-8

(1-chloro-1-phenyl-2-propylidene)cyclohexylamine

methyl N-cyclohexyl-3-phenylpropanimidate
103818-66-2

methyl N-cyclohexyl-3-phenylpropanimidate

Conditions
ConditionsYield
In tetrahydrofuran for 22h; Heating;100%
sodium methylate
124-41-4

sodium methylate

9,11-dihydro-α-ethyl-9-oxoindolizino<1,2-b>quinoline-7-acetic acid, ethyl ester
92958-06-0

9,11-dihydro-α-ethyl-9-oxoindolizino<1,2-b>quinoline-7-acetic acid, ethyl ester

9,11-dihydro-α-ethyl-9-oxoindolizino<1,2-b>quinoline-7-acetic acid, methyl ester
34141-34-9

9,11-dihydro-α-ethyl-9-oxoindolizino<1,2-b>quinoline-7-acetic acid, methyl ester

Conditions
ConditionsYield
In methanol100%
sodium methylate
124-41-4

sodium methylate

4-Chlorocarbonylmethyl-2-difluoromethyl-6-trifluoromethyl-pyridine-3,5-dicarboxylic acid dimethyl ester
124945-81-9

4-Chlorocarbonylmethyl-2-difluoromethyl-6-trifluoromethyl-pyridine-3,5-dicarboxylic acid dimethyl ester

dimethyl 2-(difluoromethyl)-4-(2-methoxy-2-oxoethyl)-6-(trifluoromethyl)-3,5-pyridinedicarboxylate
118413-16-4

dimethyl 2-(difluoromethyl)-4-(2-methoxy-2-oxoethyl)-6-(trifluoromethyl)-3,5-pyridinedicarboxylate

Conditions
ConditionsYield
In methanol for 1h;100%
sodium methylate
124-41-4

sodium methylate

Formic acid (1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-chloro-1-((R)-1,5-dimethyl-hexyl)-9a,11a-dimethyl-7-oxo-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-6a-yl ester
86477-33-0

Formic acid (1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-chloro-1-((R)-1,5-dimethyl-hexyl)-9a,11a-dimethyl-7-oxo-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-6a-yl ester

(1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-Chloro-1-((R)-1,5-dimethyl-hexyl)-6a-methoxy-9a,11a-dimethyl-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-7-one
26430-55-7, 86496-73-3

(1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-Chloro-1-((R)-1,5-dimethyl-hexyl)-6a-methoxy-9a,11a-dimethyl-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-7-one

Conditions
ConditionsYield
In tetrahydrofuran; methanol Ambient temperature;100%
sodium methylate
124-41-4

sodium methylate

Acetic acid (1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-chloro-1-((R)-1,5-dimethyl-hexyl)-9a,11a-dimethyl-7-oxo-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-6a-yl ester
86477-34-1

Acetic acid (1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-chloro-1-((R)-1,5-dimethyl-hexyl)-9a,11a-dimethyl-7-oxo-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-6a-yl ester

(1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-Chloro-1-((R)-1,5-dimethyl-hexyl)-6a-methoxy-9a,11a-dimethyl-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-7-one
26430-55-7, 86496-73-3

(1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-Chloro-1-((R)-1,5-dimethyl-hexyl)-6a-methoxy-9a,11a-dimethyl-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-7-one

Conditions
ConditionsYield
In tetrahydrofuran; methanol Ambient temperature;100%
In methanol Heating;
sodium methylate
124-41-4

sodium methylate

peracetylated α-glycosyl nitrate 2-azido-2-deoxy-D-galactopyranose
68733-05-1

peracetylated α-glycosyl nitrate 2-azido-2-deoxy-D-galactopyranose

(2R,3R,4R,5R,6R)-5-azido-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4-diol
87376-50-9

(2R,3R,4R,5R,6R)-5-azido-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4-diol

Conditions
ConditionsYield
100%
sodium methylate
124-41-4

sodium methylate

1,1-Dimethylazetidinium Perchlorate
77415-44-2

1,1-Dimethylazetidinium Perchlorate

3-(Dimethylamino)-1-propyl Methyl Ether
20650-07-1

3-(Dimethylamino)-1-propyl Methyl Ether

Conditions
ConditionsYield
In methanol at 20℃; Rate constant; Product distribution; various temperatures;100%
sodium methylate
124-41-4

sodium methylate

Benzoic acid (1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-chloro-1-((R)-1,5-dimethyl-hexyl)-9a,11a-dimethyl-7-oxo-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-6a-yl ester
86477-35-2

Benzoic acid (1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-chloro-1-((R)-1,5-dimethyl-hexyl)-9a,11a-dimethyl-7-oxo-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-6a-yl ester

(1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-Chloro-1-((R)-1,5-dimethyl-hexyl)-6a-methoxy-9a,11a-dimethyl-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-7-one
26430-55-7, 86496-73-3

(1R,3aS,3bR,5aS,6aR,8R,8aR,9aS,9bS,11aR)-8-Chloro-1-((R)-1,5-dimethyl-hexyl)-6a-methoxy-9a,11a-dimethyl-octadecahydro-cyclobuta[h]cyclopenta[a]phenanthren-7-one

Conditions
ConditionsYield
In tetrahydrofuran; methanol Ambient temperature;100%
sodium methylate
124-41-4

sodium methylate

<5-(Diphenylmethylen)-1,3-cyclopentadien-1-yl>bis(4-methylphenyl)sulfonium-perchlorat

<5-(Diphenylmethylen)-1,3-cyclopentadien-1-yl>bis(4-methylphenyl)sulfonium-perchlorat

1--2-(methoxydiphenylmethyl)cyclopentadienid

1--2-(methoxydiphenylmethyl)cyclopentadienid

Conditions
ConditionsYield
In methanol at 0℃; for 0.25h;100%
sodium methylate
124-41-4

sodium methylate

(S)-5-tosyloxypentan-4-olide
58879-34-8

(S)-5-tosyloxypentan-4-olide

3-(S)-oxiranyl-propionic acid methyl ester
85428-31-5

3-(S)-oxiranyl-propionic acid methyl ester

Conditions
ConditionsYield
In methanol for 0.333333h; Ambient temperature;100%
In methanol at 20℃; for 3h; Inert atmosphere;97%
In methanol at 20℃; for 1.5h;53%
sodium methylate
124-41-4

sodium methylate

2-(1,2,2,5,5-Pentamethyl-3-oxy-2,5-dihydro-1H-imidazol-4-yl)-1-phenyl-ethanone
129994-30-5

2-(1,2,2,5,5-Pentamethyl-3-oxy-2,5-dihydro-1H-imidazol-4-yl)-1-phenyl-ethanone

4-(2-oxo-2-phenylethyl)-1,2,2,5,5-pentamethyl-3-imidazoline oxide

4-(2-oxo-2-phenylethyl)-1,2,2,5,5-pentamethyl-3-imidazoline oxide

Conditions
ConditionsYield
With semicarbazide hydrochloride In methanol for 2.5h; Heating;100%
sodium methylate
124-41-4

sodium methylate

3-[1-Pyridin-2-yl-meth-(E)-ylidene]-3H-benzofuran-2-one
139061-35-1

3-[1-Pyridin-2-yl-meth-(E)-ylidene]-3H-benzofuran-2-one

(E)-2-(2-Hydroxy-phenyl)-3-pyridin-2-yl-acrylic acid methyl ester
139061-42-0

(E)-2-(2-Hydroxy-phenyl)-3-pyridin-2-yl-acrylic acid methyl ester

Conditions
ConditionsYield
In methanol for 2h; Ambient temperature;100%

124-41-4Upstream product

124-41-4Downstream Products

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