141263-02-7 Usage
Uses
Used in Organic Synthesis:
Ethyl 2,3,6-tri-O-benzyl-1-thio-b-D-glucopyranoside is used as a protecting group in organic synthesis for the synthesis of complex carbohydrates and glycosides. Its benzyl groups protect the hydroxyl groups during the reaction, allowing for selective reactions to occur at other sites on the molecule.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, Ethyl 2,3,6-tri-O-benzyl-1-thio-b-D-glucopyranoside is used as a key intermediate in the preparation of various bioactive molecules and pharmaceuticals. Its unique structure and reactivity enable the synthesis of compounds with potential therapeutic applications.
Used in Carbohydrate Chemistry:
Ethyl 2,3,6-tri-O-benzyl-1-thio-b-D-glucopyranoside is used as a building block in carbohydrate chemistry for the construction of complex carbohydrate structures. Its sulfur atom linked to the anomeric carbon allows for the formation of glycosidic bonds with other carbohydrate units, facilitating the synthesis of diverse oligosaccharides and polysaccharides.
Used in Materials Science:
In materials science, Ethyl 2,3,6-tri-O-benzyl-1-thio-b-D-glucopyranoside is used as a component in the development of novel materials with specific properties. Its ability to form glycosidic bonds and its compatibility with various synthetic strategies make it a promising candidate for the creation of advanced materials with applications in areas such as drug delivery, sensors, and biomaterials.
Check Digit Verification of cas no
The CAS Registry Mumber 141263-02-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,1,2,6 and 3 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 141263-02:
(8*1)+(7*4)+(6*1)+(5*2)+(4*6)+(3*3)+(2*0)+(1*2)=87
87 % 10 = 7
So 141263-02-7 is a valid CAS Registry Number.
141263-02-7Relevant articles and documents
Picoloyl protecting group in synthesis: Focus on a highly chemoselective catalytic removal
Bandara, Mithila D.,Demchenko, Alexei V.,Geringer, Scott A.,Mannino, Michael P.
, p. 4863 - 4871 (2020/07/13)
The picoloyl ester (Pico) has proven to be a versatile protecting group in carbohydrate chemistry. It can be used for the purpose of stereocontrolling glycosylations via an H-bond-mediated Aglycone Delivery (HAD) method. It can also be used as a temporary protecting group that can be efficiently introduced and chemoselectively cleaved in the presence of practically all other common protecting groups used in synthesis. Herein, we will describe a new method for rapid, catalytic, and highly chemoselective removal of the picoloyl group using inexpensive copper(ii) or iron(iii) salts. This journal is
PARTIAL SUBSTITUTION OF THIOGLYCOSIDES BY PHASE TRANSFER CATALYZED BENZOYLATION AND BENZYLATION
Garegg, Per J.,Kvarnstroem, Ingemar,Niklasson, Annika,Niklasson, Gunilla,Svensson, Stefan C. T.
, p. 933 - 954 (2007/10/02)
Partial substitution by phase transfer catalysis giving monobenzoylated and monobenzylated products from 2,3- and from 4,6-diols in ethyl 1-thio-D-hexopyranosides with the β-gluco, β-galacto- and α-manno-configurations are described.Two disaccharide thiog
Synthesis of trisaccharide methyl glycosides related to fragments of the capsular polysaccharide of Streptococcus pneumoniae type 18C
Van Steijn,Kamerling,Vliegenthart
, p. 229 - 245 (2007/10/02)
The synthesis is reported of methyl 3-0-(4-0-β-D-galactopyranosyl-α-D-glucopyranosyl)-α-L- rhamnopyranoside (1), methyl 2-0-α-D-glucopyranosyl-4-0-β-D-glucopyranosyl-β-D- galactopyranoside (3), methyl 3-0-(4-0-β-D-galactopyranosyl-α-D-glucopyranosyl)-α-L-
