Synthesis of neodesmosine, a crosslinking pyridinium amino acid of elastin, via a Negishi cross-coupling
Neodesmosine, isolated from the hydrolysate of bovine ligamentum nuchae, is a crosslinking pyridinium amino acid of elastin. In this study, the first total synthesis of neodesmosine is reported via a Negishi cross-coupling reaction between 3,5-dihalogenated pyridines and the corresponding iodo amino acid.
Yanuma, Hiroto,Usuki, Toyonobu
p. 55 - 63
(2013/03/13)
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