- Synthesis of Poly(p-styrene) and Its Reactivity with Nitrogen Dioxide
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Poly(p-styrene) (polyPBN) has been prepared by using p-chlorostyrene as a starting material.The reaction of polyPBN with nitrogen dioxide (NO2) and its efficiency for radical trapping were studied.The stability of NO2 adduct of polyPBN and operational simplicity to recover polyPBN showed that polyPBN is applicable to the removal of NO2 in atmosphere.
- Ren, Jingzhu,Sakakibara, Kazuhisa,Hirota, Minoru
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- The Synthesis of Poly and Characterizations of Reaction with Nitrogen Dioxide
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Polymer-supported spin trap, poly (polyPBN), was prepared by using p-chlorostyrene as a starting material, followed by Grignard reaction, condensation with t-butylamine, reduction, polymerization, and oxidation.The adsorption ability of No2 by polyPBN was investigated in a closed-circulation system.PolyPBN maintains its original NO2 adsorbing ability in the mixed gas of nitrogen and nitrogen dioxide saturated with water vapor even after repeated (5 times) use.However, when the gaseous phase is freed from water, polyPBN exhibits less efficiency to adsorb NO2 and its adsorbing ability decreases gradually with the repeated use.
- Ren, Jingzhu,Sakakibara, Kazuhisa,Hirota, Minoru
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