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144261-46-1

2-Propenoic acid (3-methoxyphenyl)methyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 144261-46-1 Structure

  • Basic information

    1. Product Name: 2-Propenoic acid (3-methoxyphenyl)methyl ester
    2. Synonyms: 3-(4-METHOXYPHENYL)-2-PROPENOIC ACID METHYL ESTER;4-METHOXYCINNAMIC ACID METHYL ESTER;METHYL P-METHOXYCINNAMATE;METHYL 4-METHOXYCINNAMATE;SPECS AE-641/05563005;P-MethoxylMethylCinnamate;P-MethoxylCinnamaldehydeIsooctyl;p-Methoxyl
    3. CAS NO:144261-46-1
    4. Molecular Formula: C11H12O3
    5. Molecular Weight: 192.21
    6. EINECS: 1533716-785-6
    7. Product Categories: N/A
    8. Mol File: 144261-46-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 276 °C
    3. Flash Point: 110 °C
    4. Appearance: /
    5. Density: 1.080
    6. Vapor Pressure: 0.00499mmHg at 25°C
    7. Refractive Index: 1.51
    8. Storage Temp.: 2-8°C
    9. Solubility: N/A
    10. CAS DataBase Reference: 2-Propenoic acid (3-methoxyphenyl)methyl ester(CAS DataBase Reference)
    11. NIST Chemistry Reference: 2-Propenoic acid (3-methoxyphenyl)methyl ester(144261-46-1)
    12. EPA Substance Registry System: 2-Propenoic acid (3-methoxyphenyl)methyl ester(144261-46-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 144261-46-1(Hazardous Substances Data)

144261-46-1 Usage

Chemical Properties

White crystalline solid

Check Digit Verification of cas no

The CAS Registry Mumber 144261-46-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,4,2,6 and 1 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 144261-46:
(8*1)+(7*4)+(6*4)+(5*2)+(4*6)+(3*1)+(2*4)+(1*6)=111
111 % 10 = 1
So 144261-46-1 is a valid CAS Registry Number.
InChI:InChI=1/C11H12O3/c1-3-11(12)14-8-9-5-4-6-10(7-9)13-2/h3-7H,1,8H2,2H3

144261-46-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (3-methoxyphenyl)methyl prop-2-enoate

1.2 Other means of identification

Product number -
Other names (3-METHOXYPHENYL)METHYL 2-PROPENOATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:144261-46-1 SDS

144261-46-1Relevant articles and documents

Ruthenium(II)-Catalyzed Highly Chemo- And Regioselective Oxidative C6 Alkenylation of Indole-7-carboxamides

Jadhav, Pankaj P.,Kahar, Nilesh M.,Dawande, Sudam G.

supporting information, p. 8673 - 8677 (2021/11/20)

We disclosed the first efficient method for highly chemo- and regioselective C6 alkenylation of indole-7-carboxamides using inexpensive Ru(II) catalyst through chelation assisted C-H bond activation. Electronically diverse indole-7-carboxamides and alkenes react efficiently to produce a wide range of C6 alkenyl indole derivatives. Further the C6 alkenyl indole-7-carboxamides modified to their derivatives through simple chemical transformations. The observed regioselectivity and kinetics has been evidenced by deuterium incorporation and intermolecular competitive studies. In addition, for mechanistic insights, the intermediates were analyzed by HRMS.

Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer

Yamamoto, Eiji,Hilton, Margaret J.,Orlandi, Manuel,Saini, Vaneet,Toste, F. Dean,Sigman, Matthew S.

supporting information, p. 15877 - 15880 (2016/12/23)

Enantioselective 1,1-diarylation of terminal alkenes enabled by the combination of Pd catalysis with a chiral anion phase transfer (CAPT) strategy is reported herein. The reaction of substituted benzyl acrylates with aryldiazonium salts and arylboronic acids gave the corresponding 3,3-diarylpropanoates in moderate to good yields with high enantioselectivies (up to 98:2 er). Substituents on the benzyl acrylate and CAPT catalyst significantly affect the enantioselectivity, and multidimensional parametrization identified correlations suggesting structural origins for the high stereocontrol.

The 'Baylis - Hillman reaction' mechanism and applications revisited

Fort, Yves,Berthe, Marie Christine,Caubere, Paul

, p. 6371 - 6384 (2007/10/02)

It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1,4-diazabicyclo[2.2.2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.

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