145745-05-7 Usage
Uses
Used in Pharmaceutical Industry:
(4-Benzyloxyphenyl)tributylstannane is used as a synthetic reagent for the preparation of complex organic molecules, particularly in the synthesis of pharmaceutical compounds. Its ability to participate in Stille coupling reactions allows for the formation of diverse molecular structures, which can be further utilized in drug development.
Used in Chemical Research:
In the field of chemical research, (4-Benzyloxyphenyl)tributylstannane is used as a key intermediate for the synthesis of various organic compounds. Its reactivity in Stille coupling reactions enables the creation of epoxy-substituted aryl alkenes and polycyclic meroterpenoids, which are important building blocks in organic chemistry.
Used in Material Science:
(4-Benzyloxyphenyl)tributylstannane is employed as a reagent in the development of new materials, such as polymers and advanced materials with specific properties. Its role in Stille coupling reactions allows for the creation of novel molecular structures that can be tailored for various applications in material science.
Check Digit Verification of cas no
The CAS Registry Mumber 145745-05-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,5,7,4 and 5 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 145745-05:
(8*1)+(7*4)+(6*5)+(5*7)+(4*4)+(3*5)+(2*0)+(1*5)=137
137 % 10 = 7
So 145745-05-7 is a valid CAS Registry Number.
145745-05-7Relevant articles and documents
Nickel-catalyzed decarbonylative stannylation of acyl fluorides under ligand-free conditions
Wang, Xiu,Wang, Zhenhua,Liu, Li,Asanuma, Yuya,Nishihara, Yasushi
, (2019/05/24)
Nickel-catalyzed decarbonylative stannylation of acyl fluorides under ligand-free conditions was disclosed. A variety of aromatic acyl fluorides are capable of reacting with silylstannanes in the presence of cesium fluoride. A one-pot decarbonylative stannylation/Migita-Kosugi-Stille reaction of benzoyl fluoride, giving rise to the direct formation of the corresponding cross-coupled products, further demonstrated the synthetic utility of the present method. This newly developed methodology with a good functional-group compatibility via C-F bond cleavage and C-Sn bond formation under nickel catalysis opens a new area for the functionalization of acyl fluorides in terms of carbon-heteroatom bond formation.
