- Anodic dissolution of tin in alcohols
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Tin(II) alcoholates Sn(OR)2 are formed upon the anodic galvanostatic dissolution of tin in alcohols in an undivided cell in the presence of minimum amounts of NaOAc as an electrolyte. Tin(II) alcoholates are easily hydrolyzed in air to form oxy
- Vereshchagin,Elinson,Goloveshkin,Novikov,Egorov
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p. 840 - 843
(2016/12/27)
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- A new method for synthesizing dialkoxytin(II) and mono and diaryloxytin(II) compounds
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The reactions of bis(β-diketonato)tin(II), such as bis(2, 4-pentanedionato)tin(II), Sn(acac)2, bis(1-ethoxy-1, 3-butanedionato)tin(II), Sn(etac)2, and bis(1-methoxy-1, 3-butanedionato)-tin(II), Sn(mtac)2, with sodium alkoxide (NaOR, R = CH3, C2H5) in alcohol/benzene at room temperature have been found to give the corresponding dialkoxytin(II) compounds. Sn(acac)2 reacted also with o-substituted phenols [O-X-C6H4OH; X = CH3CO, CH3OC(O), CH3O, Cl, (CH3)3C] in a molar ratio of 1:2 at 90°C to afford the corresponding monosubstituted tin(II) compound, [Sn(OC6H4-X)(acac)], but the reaction with C6H5OH produced only the diphenoxide, Sn(OC6H5)2.
- Wakeshima, Ikuko,Suzuki, Toshitaka,Takemoto, Akihiko,Kijima, Ichiro
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p. 787 - 796
(2008/10/09)
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