148854-09-5

Basic information

• Product Name: Benzene, 1-bromo-3-isocyano- (9CI)
• Synonyms: Benzene, 1-bromo-3-isocyano- (9CI)
• CAS NO: 148854-09-5
• Molecular Formula: C₇H₄BrN
• Molecular Weight: 182.01736
• Product Categories: ISONITRITE
• Mol File: 148854-09-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1-bromo-3-isocyano- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-3-isocyano- (9CI)(148854-09-5)
• EPA Substance Registry System: Benzene, 1-bromo-3-isocyano- (9CI)(148854-09-5)

Safety Data

• Hazardous Substances Data: 148854-09-5(Hazardous Substances Data)

Upstream product

• 37831-25-7 N-(3-bromophenyl)formamide 
• 591-19-5 m-Bromoaniline 

Downstream Products

• 1311947-45-1 N-(3-bromophenyl)-N-formyl-4-nitrobenzamide 
• 1414349-70-4 N-(3-bromophenyl)-N-formyl-2-(thiophen-2-yl)acetamide 
• 25216-74-4 tert-butyl (3-bromophenyl)carbamate 

Relevant articles and documents

Silver-Catalyzed Chemoselective [4+2] Annulation of Two Isocyanides: A General Route to Pyridone-Fused Carbo- and Heterocycles

A silver-catalyzed chemoselective [4+2] annulation of aryl and heteroaryl isocyanides with α-substituted isocyanoacetamides was developed for the facile and efficient synthesis of 2-aminoquinolones, naphthyridines, and phenanthrolines. A mechanism for this multistep domino reaction is proposed on the basis of a13C-labeling experiment, according to which an unprecedented chemoselective heterodimerization of two different isocyanides generates an α-amidoketenimine intermediate, which undergoes 1,3-amino migration to form an α-imidoylketene, followed by 6 π electrocyclization.

MULTICYCLIC COMPOUND HAVING NITROGEN AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME

The present invention relates to a nitrogen-containing polycyclic compound employing a novel structure and an organic light emitting device using the same. According to the present invention, the nitrogen-containing polycyclic compound can be used to form an organic layer in the organic light emitting device.COPYRIGHT KIPO 2015

On the reaction of carboxylic acids and isonitriles with conventional heating

Control over the formation of N-formylamides versus the formation of captodative alkenes from the reaction of arylacetic acids with isonitriles has been achieved. Low temperatures and high concentrations favor alkenes, and high temperatures and low concen

Facile reaction of carboxylic acids with isonitriles in toluene

Isonitriles react with low concentrations of carboxylic acids in toluene at 110 °C to give N-formylamides in yields generally above 70%. These concentrations can be obtained either by syringe pump addition of a toluene solution of the acid, or by using a suspension of the acid if it has limited solubility in toluene at room temperature.