Acid-base properties and stability of sulfoxylic acid in aqueous solutions
A comparative study of decomposition of sulfoxylic acid S(OH)2 and sulfoxylate anion and their reactions with formaldehyde in aqueous solutions with different acidity was carried out. Using the obtained results, the pK 1 value of S(OH)2 was determined for the first time. Pleiades Publishing, Ltd., 2010.
α-hydroxysulfinates 1 (table 1) are synthesized (path b, Fig. 1), by slowly adding aldehydes 3 to the mixture sodium dithionite 4 - sodium hydroxide.Owing to their limited stability the products 1 are readily separated from sodium sulfite 5 and isolated.They are easily distinguished (table 2) from their oxydation counterparts 2.
Mulliez, Michel,Naudy, Carole
p. 2469 - 2476
(2007/10/02)
FACTORS DETERMINING THE REACTIVITY OF ELECTROLYTIC ZINC POWDERS
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Aleksandrova, A. N.,Budanov, V. V.
p. 408 - 410
(2007/10/02)
INFLUENCE OF THE CONDITIONS OF ELECTRODEPOSITION OF DISPERSED ZINC ON ITS ACTIVITY IN SYNTHESIS OF RONGALITE
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Aleksandrova, A. N.,Shibaeva, I. A.,Budanov, V. V.