Photoinduced Novel Silylation of CF3-substituted Benzenes with Disilane and Trisilane
Irradiation of CF3-substituted benzene in the presence of hexamethyldisilane and octamethyltrisilane causes two types of photosilylation, namely one at a benzylic position to give the corresponding benzylic silanes, and the other at aromatic ring to afford the corresponding phenylsilanes.
Selective electrochemical synthesis and reactivity of functional benzylic fluorosilylsynthons
Electrochemical reductive silylation of meta-(trifluoromethyl)arenes by the sacrificial anode technique selectively led to meta-trimethylsilyldifluoromethylarenes (ArCF2TMS), in the presence of an excess of TMSCl and in a THF/cosolvent mixture
Clavel, Philippe,Lessene, Guillaume,Biran, Claude,Bordeau, Michel,Roques, Nicolas,Trévin, Stéphane,Montauzon, Dominique De
p. 301 - 310
(2007/10/03)
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