Photoinduced Novel Silylation of CF3-substituted Benzenes with Disilane and Trisilane

DOI: 10.1039/c39930000678

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 678 - 680 (1993)

Update date:2022-08-29

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Authors:

Kako, Masahiro

Morita, Takahiro

Torihara, Tetsuya

Nakadaira, Yasuhiro

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Article abstract of DOI:10.1039/c39930000678

Irradiation of CF3-substituted benzene in the presence of hexamethyldisilane and octamethyltrisilane causes two types of photosilylation, namely one at a benzylic position to give the corresponding benzylic silanes, and the other at aromatic ring to afford the corresponding phenylsilanes.

Full text of DOI:10.1039/c39930000678

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