- Synthesis of carbon-14 labeled ZJ0712, a novel strobilurin fungicide
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ZJ0712, a broad-spectrum fungicidal ingredient of strobilurin, exhibits a high protective and curative activity against plant pathogenic fungi. To support the study on its metabolism, residue, environmental behavior, and fate for safety evaluation, two versions of carbon-14 labeled ZJ0712, methyl (E)-2-(2-((2,5-dimethylphenoxy)methyl)phenyl)-3-methoxy[2-14C]acrylate (2) and methyl (E)-2-(2-((2,5-dimethyl[phenyl-U-14C6]phenoxy)methyl)phenyl)-3-methoxyacrylate (3), were synthesized from barium [14C]carbonate in 6-step yield of 47% and from 2,5-dimethyl[phenyl-U-14C6]phenol in the yield of 91%, respectively.
- Yang, Zheng-Min,Xu, Ya-Jun,Zhang, Gui-Hua,Jian, Cai-Guang,Li, Xiao,Ye, Qing-Fu
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p. 812 - 819
(2018/07/30)
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- Process for producing α-ketoamide derivative
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There is disclosed an efficient process for producing α-ketoacetamide of the formula: STR1 which is useful as an intermediate for the production of various alkoxyiminoacetamide compounds to be used for agricultural fungicides. In this process, a correspon
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