150630-79-8Relevant articles and documents
Aryne-Mediated [2,3]-Sigmatropic Rearrangement of Tertiary Allylic Amines
Zhang, Juan,Chen, Zhi-Xiong,Du, Ting,Li, Bing,Gu, Yonghong,Tian, Shi-Kai
supporting information, p. 4872 - 4875 (2016/10/18)
A new strategy has been established for the [2,3]-sigmatropic rearrangement of quaternary allylic ammonium ylides via in situ activation of tertiary allylic amines with arynes under mild conditions. Using 2-(trimethylsilyl)aryl triflates as aryne precurso
On the Conformation of Fused Five-Membered Heterocyclic Rings Derived from the Intramolecular Oxime Olefin Cycloaddition Reaction
Hassner, Alfred,Maurya, Rakesh,Friedman, Oded,Gottlieb, Hugo E.,Padwa, Albert,Austin, David
, p. 4539 - 4546 (2007/10/02)
Thermal intramolecular oxime olefin cycloaddition of α-allylamino aldoximes and ketoximes 4 led stereospecifically to formation of oxadiazabicyclooctanes 6.The presence of heteroatoms in these bicyclic fused 5-membered rings permits for the first t