cas 1520-46-3, 1,3-DIPHENYL-2-METHYLPROPANE | Articles data ｜lookchem

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1520-46-3

Articles about 1520-46-3Total 2 be found

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Iron-Catalyzed Remote Arylation of Aliphatic C-H Bond via 1,5-Hydrogen Shift
Catalytic amounts of an iron(III) salt and a N-heterocyclic carbene ligand catalyze the arylation of 2-iodoalkylarenes with diphenylzinc selectively at the C-H bond of the alkyl side chain. Several lines of evidence suggest that the iron catalyst reacts with the aryl iodide moiety of the substrate to generate an aryliron intermediate that behaves in a radical manner and cleaves the aliphatic C-H bond through 1,5-hydrogen transfer; the resulting alkyliron intermediate undergoes reductive elimination to give the arylated product.
Zhou, Bingwei,Sato, Hiroki,Ilies, Laurean,Nakamura, Eiichi
p. 8 - 11
(2018/01/17)

A New and Practical Method of Decarboxylation: Photosensitized Decarboxylation of N-Acyloxyphthalimides via Electron-Transfer Mechanism
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Okada, Keiji,Okamoto, Kazushige,Oda, Masaji
p. 8736 - 8738
(2007/10/02)

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Chemical Properties

Melting Point: -33.7°C
Boiling Point: 300°Cat760mmHg
Flash Point:138.1°C
Density: 0.972g/cm³
Refractive Index: 1.5449 (estimate)
PSA: 0.00000
LogP: 4.10790

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