Ruthenium catalyzed selective hydrosilylation of aldehydes
A chemoselective hydrosilylation method for aldehydes is developed using a ruthenium catalyst [(Ru(p-cymene)Cl2)2] and triethylsilane; a mono hydride bridged dinuclear complex [{(η6-p- cymene)RuCl}2(μ-H-μ-Cl)] a
Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions
The readily-accessible, air-stable Lewis acid [(terpy)PPh][B(C6F5)4]21 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.
Andrews, Ryan J.,Chitnis, Saurabh S.,Stephan, Douglas W.
supporting information
p. 5599 - 5602
(2019/05/21)
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