15304-57-1Relevant articles and documents
Crystal and Molecular Structure of Diindium Triphthalocyaninate at 300 K
Janczak, Jan,Kubiak, Ryszard
, p. 3809 - 3812 (1993)
The new complex diindium triphthalocyaninate has been synthesized in crystalline form from the reaction of In-Sn alloy with 1,2-dicyanobenzene at 210 deg C.It crystallizes in the triclinic system, space group P with Z = 1 in a unit cell of dimensions a = 14.492(3), b = 13.179(3), c = 11.493(2) Angstroem, α = 113.96(2), β = 97.15(2) and γ = 66.13(2) deg.The structure was solved by Patterson and Fourier difference methods and refined by block-diagonal least-squares techniques to R = 0.0282, R' = 0.0372 and S = 1.22 for 7019 independent reflections having F0 > 4?(F).The centrosymmetric molecule consists of three phthalocyaninate ligands and two indium anions.The planes of the two peripheral ligands are parallel to each other, while the third central ligand is rotated about 37.5 deg in relation to the peripheral rings.The mean intramolecular distance between phthalocyanine planes is 2.954(5) Angstroem.The angle of inclination of the central to the peripheral planes is 5.2 deg.The indium anions are located between the phthalocyaninate ligands and have six-co-ordinate geometry.The four In-N bonds involving isoindole nitrogens from peripheral phthalocyaninates are shorter than the two involving isoindole nitrogens from the central phthalocyaninate .The intramolecular distance between indium atoms is 4.036(5) Angstroem.The shortest intermolecular distance between neighbouring successive phthalocyanine planes is 3.477(5) Angstroem.
Improved performance of organic light-emitting diodes using a metal-phthalocyanine hole-injection layer
Kao, Po-Ching,Chu, Sheng-Yuan,Liu, Shyh-Jiun,You, Zong-Xian,Chuang, Chan-An
, p. H122-H126 (2008/10/09)
In this paper, we systematically investigated the physical characteristics of the various metal phthalocyanines (MPcs) and the influence of the MPcs hole-injection layer on the electroluminescence performance of indium tin oxide/MPc/naphthylphenylbiphenyl diamine (NPB)/ Al q3 LiFAl devices. The characteristics were measured at room temperature with a thickness variation of the MPc layer. The individual highest occupied and lowest unoccupied molecular orbital (HOMO and LUMO) energies of MPcs were derived from the photoelectron emission and the optical absorption measurements. The results showed that the HOMO and LUMO level energies of MPcs are dependent on their central metal atoms. The turn-on voltage for the devices is lowered by inserting MPc layers and remains virtually the same as the MPc layer thickness is adjusted in the range of 5-15 nm. In addition, the turn-on voltage decreases significantly with the increase of the HOMO levels of the MPc films, demonstrating that the MPc/NPB interface instead of the ITO/MPc interface plays an important role in the hole injection.
X-ray analysis of phthalocyanines formed in the reaction of Au-Cu and Au-Sn alloys with 1,2-dicyanobenzene
Kubiak, Ryszard,Janczak, Jan
, p. 107 - 112 (2008/10/08)
X-ray investigations of the reactions of copper, tin and their alloys with gold, with 1,2-dicyanobenzene at 210°C have been performed. It was found that under the conditions used, gold does not take part in the reaction with 1,2-dicyanobenzene, but separates from the alloys. Copper and tin phthalocyanines are formed as the main products of the above reactions. The crystal structure of tin phthalocyanine (SnPC) has been determined. SnPc crystallizes in the triclinic system (a = 12.048(3) A, b = 12.630(3) A, c = 8.671(3) A, α = 95.85(5)°, β = 95.10(5)°, γ = 68.25(5)°), space group P1, Z = 2. The refined structure with anisotropic temperature factors have R = 0.041. The Sn atom is coordinated by four isoindole N atoms, the average Sn-N distance being 2.267(6) A. The SnPc molecule is not planar. The Sn atom is 1.1286 A out of the plane of the four coordinating N atoms.
SYNTHESIS OF METALLOPHTHALOCYANINES FROM PHTALONITRILE WITH STRONG ORGANIC BASES
Tomoda, Haruhiko,Saito, Shojiro,Shiraishi, Shinsaku
, p. 313 - 316 (2007/10/02)
Several metallophthalocyanines (MPc: M=Ni(II), Co(II), Zn(II), Pb(II), Fe(II), Sn(II), Cd(II), Mg(II), and Mn(III)) were obtained by heating phthalonitrile with metal salts in alcohols in the presence of 1,8-diazabicycloundec-7-ene.Metal acetylacet
SYNTHESIS AND PROPERTIES OF A NEW KIND OF ONE-DIMENSIONAL C0NDUCTOR VIII. SYNTHESIS AND CHARACTERIZATION OF trans-BIS-1-ALKYNYL SUBSTITUTED SILICON, GERMANIUM, TIN PHTHALOCYANINES AND GERMANIUM HEMIPORPHYRAZINES
Hanack, Michael,Mitulla, Konrad,Pawlowski, Georg,Subramanian, L. R.
, p. 315 - 326 (2007/10/02)
The preparation of several new trans-bis-1-alkynyl(phthalocyaninato)silicon (VIc-f), -germanium(VIIc-f) and -tin(VIIId,f) compounds as well as trans-bis-1-alkynyl(hemiporphyrazinato)germanium (XIc, e, f) derivatives is described.The products were obtained
