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153861-59-7

Carbamic acid, [[2-(hydroxymethyl)cyclopropyl]methyl]-, 1,1-dimethylethyl is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • ((1R,2S)-2-Hydroxymethyl-cyclopropylmethyl)-carbamic acid tert-butyl ester

    Cas No: 153861-59-7

  • USD $ 1.9-2.9 / Gram

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  • 153861-59-7 Structure

  • Basic information

    1. Product Name: Carbamic acid, [[2-(hydroxymethyl)cyclopropyl]methyl]-, 1,1-dimethylethyl
    2. Synonyms: N-Boc((1R,2S)-2-(aminomethyl)cyclopropyl)methanol;tert-butyl N-{[(1R,2S)-2-(hydroxymethyl)cyclopropyl]methyl}carbamate;Carbamic acid, [[2-(hydroxymethyl)cyclopropyl]methyl]-, 1,1-dimethylethyl ester, (1R-cis)- (9CI)
    3. CAS NO:153861-59-7
    4. Molecular Formula: C10H19NO3
    5. Molecular Weight: 201.26
    6. EINECS: N/A
    7. Product Categories: N-BOC
    8. Mol File: 153861-59-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Carbamic acid, [[2-(hydroxymethyl)cyclopropyl]methyl]-, 1,1-dimethylethyl(CAS DataBase Reference)
    10. NIST Chemistry Reference: Carbamic acid, [[2-(hydroxymethyl)cyclopropyl]methyl]-, 1,1-dimethylethyl(153861-59-7)
    11. EPA Substance Registry System: Carbamic acid, [[2-(hydroxymethyl)cyclopropyl]methyl]-, 1,1-dimethylethyl(153861-59-7)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 153861-59-7(Hazardous Substances Data)

153861-59-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 153861-59-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,3,8,6 and 1 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 153861-59:
(8*1)+(7*5)+(6*3)+(5*8)+(4*6)+(3*1)+(2*5)+(1*9)=147
147 % 10 = 7
So 153861-59-7 is a valid CAS Registry Number.

153861-59-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name ((1R,2S)-2-Hydroxymethyl-cyclopropylmethyl)-carbamic acid tert-butyl ester

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:153861-59-7 SDS

153861-59-7Downstream Products

153861-59-7Relevant articles and documents

Cyclopropane-based conformational restriction of GABA by a stereochemical diversity-oriented strategy: Identification of an efficient lead for potent inhibitors of GABA transports

Nakada, Kazuaki,Yoshikawa, Mamie,Ide, Soichiro,Suemasa, Akihiro,Kawamura, Shuhei,Kobayashi, Takaaki,Masuda, Eiji,Ito, Yoshihiko,Hayakawa, Wataru,Katayama, Takahiro,Yamada, Shizuo,Arisawa, Mitsuhiro,Minami, Masabumi,Shuto, Satoshi

, p. 4938 - 4950 (2013/09/02)

A series of cyclopropane-based conformationally restricted γ-aminobutyric acid (GABA) analogs with stereochemical diversity, that is, the trans- and cis-2,3-methano analogs Ia and Ib and their enantiomers ent-Ia and ent-Ib, and also the trans- and cis-3,4

Synthesis of Optically Active cis- and trans-1,2-Disubstituted Cyclopropane Derivatives by the Simmons-Smith Reaction of Allyl Alcohol Derivatives Derived from (R)-2,3-O-Isopropylideneglyceraldehyde

Morikawa, Tsutomu,Sasaki, Hirofumi,Hanai, Ryo,Shibuya, Akira,Taguchi, Takeo

, p. 97 - 103 (2007/10/02)

The Simmons-Smith reactions of Z- and E-allyl alcohol derivatives 6 derived from (R)-2,3-O-isopropylideneglyceraldehyde (5) were used for the synthesis of optically active cis- and trans-1,2-disubstituted cyclopropane derivatives.Reaction of 6 with diethyl zinc and diiodomethane gave cyclopropane derivatives 7 in 84percent to quantitative yields with 35 to ca. 100percent des.Identical facial selectivities toward the double bonds, 1re-2si for Z-6 and 1re-2re for E-6, were observed in the cyclopropanations.The diastereoselectivity was dependent on the protecting group on the terminal allylic oxygen (R of 6, TBDPS > MOM > Bn) and on the stereochemistry of the double bond (Z > E).For TBDPS ethers Z- and E-6c, cis- and trans-7c were obtained as single diastereomers, respectively.It was clearly demonstrated that the stereoselectivity of the cyclopropanation is controlled by the directing effect of the allylic oxygen (O-1) of the dioxolane ring, which coordinates to the reagent.The terminal allylic oxygen (O-2) lowered the diastereoselectivity.This reaction was applied to the synthesis of optically active cyclopropane analogs of γ-aminobutyric acid (GABA) 18, 22, and ent-22.

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