154469-74-6Relevant articles and documents
Synthesis method of cis alpha halogenated alpha, beta-unsaturated ketones
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Paragraph 0049; 0051; 0052, (2019/01/05)
The invention discloses a synthesis method of cis alpha halogenated alpha, beta-unsaturated ketones represented by the formula (III). According to the synthesis method, compounds represented by the formula (I), compounds represented by the formula (II), I
One-Step Preparation of α-Chloro-α,β-unsaturated Carbonyl Compounds by the Reaction of Silyl Enol Ethers with TiCl4-LiAlH4-CCl4
Mitani, Michiharu,Kobayashi, Yoshinori
, p. 284 - 286 (2007/10/02)
Reaction of silyl enol ethers in a system composed of TiCl4, LiAlH4, and CCl4, which generates dichlorocarbene, produced α-chloro-α,β-unsaturated carbonyl compounds in an one-step process.