Double asymmetric induction in the synthesis of enantiomeric α-aminophosphonic acids mediated by sulfinimines
A double asymmetric induction in the synthesis of α-aminophosphonic acids is described. It involves the nucleophilic addition of anions of enantiomeric dimenthyl phosphites to both (+)-(S)- and (-)-(R)-enantiomers of N-(p-tolylsulfinyl)benzaldimine and subsequent acidic hydrolysis of the adducts formed. The match and mismatch effects were observed.
Lyzwa, Piotr
p. 15 - 19
(2014/02/14)
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