1567840-97-4

Basic information

• Product Name: (+)-di-(1R,2S,5R)-menthyl (S_S,R_C)-1-phenyl-1-(p-tolylsulfinylamino)-methanephosphonate
• Synonyms: (+)-di-(1R,2S,5R)-menthyl (S_S,R_C)-1-phenyl-1-(p-tolylsulfinylamino)-methanephosphonate
• CAS NO: 1567840-97-4
• Molecular Weight: 601.831
• Mol File: 1567840-97-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+)-di-(1R,2S,5R)-menthyl (S_S,R_C)-1-phenyl-1-(p-tolylsulfinylamino)-methanephosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-di-(1R,2S,5R)-menthyl (S_S,R_C)-1-phenyl-1-(p-tolylsulfinylamino)-methanephosphonate(1567840-97-4)
• EPA Substance Registry System: (+)-di-(1R,2S,5R)-menthyl (S_S,R_C)-1-phenyl-1-(p-tolylsulfinylamino)-methanephosphonate(1567840-97-4)

Safety Data

• Hazardous Substances Data: 1567840-97-4(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 105449-76-1 di(1R,2S,5R)-menthyl phosphorochloridite 
• 188447-91-8 (S)-p-toluenesulfinimide 
• 100-52-7 benzaldehyde 
• 211183-18-5 hydrogen di[(1R,2S,5R)-menthyl] phosphite 
• 153277-49-7 (S)-N-benzylidene-4-toluenesulfinamide 

Downstream Products

• 37714-05-9 (R)-1-amino-1-phenylmethylphosphonic acid 

Relevant articles and documents

Double asymmetric induction in the synthesis of enantiomeric α-aminophosphonic acids mediated by sulfinimines

A double asymmetric induction in the synthesis of α-aminophosphonic acids is described. It involves the nucleophilic addition of anions of enantiomeric dimenthyl phosphites to both (+)-(S)- and (-)-(R)-enantiomers of N-(p-tolylsulfinyl)benzaldimine and subsequent acidic hydrolysis of the adducts formed. The match and mismatch effects were observed.