N-TRIMETHYLSILYL DERIVATIVES OF THIOLACTAMS IN THE SILYL VERSION OF N-AMIDO- AND N-SULFONAMIDOALKYLATION
N-Trimethylsilylthiolactams react with N-chloromethyllactams and -sulfonamides to give the corresponding N-amido- and N-sulfonylamidomethyl derivatives of thiolactams in fairly high yields. By contrast, products of addition of N-trimethylsilylthiolactams to aldehydes do not react as amidoalkylating agents with N-trimethylsilyllactams.
Sergeev, V. N.,Artamkin, S. A.,Baukov, Yu. I.
p. 1598 - 1601
(2007/10/02)
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